Epoxidation of Oleic Acid Catalyzed by Peroxo Phosphotungstate in a Two-Phase System
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
|
| Output data |
Year: 1998,
Volume: 134,
Number: 1-3,
Pages: 223-228
Pages count
: 6
DOI:
10.1016/S1381-1169(98)00039-9
|
| Tags |
Epoxidation, Oleic acid, Polyoxometalates |
| Authors |
Kozhevnikov I.V.
,
Mulder G.P.
,
Steverink-de Zoete M.C.
,
Oostwalb M.G.
|
| Affiliations |
| 1 |
The University of Liverpool
|
| 2 |
Unichema International
|
|
Funding (1)
The peroxo phosphotungstate {PO4[WO(O2)2]4}3− is a highly efficient catalyst (or catalyst precursor) for the phase-transfer epoxidation of oleic acid by aqueous 35–60% hydrogen peroxide, yielding 84% epoxide (based on oleic acid) at 95% oleic acid conversion and 800–1200 catalyst turnovers, without using a chlorocarbon solvent.