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Epoxidation of Oleic Acid Catalyzed by Peroxo Phosphotungstate in a Two-Phase System Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Output data Year: 1998, Volume: 134, Number: 1-3, Pages: 223-228 Pages count : 6 DOI: 10.1016/S1381-1169(98)00039-9
Tags Epoxidation, Oleic acid, Polyoxometalates
Authors Kozhevnikov I.V. , Mulder G.P. , Steverink-de Zoete M.C. , Oostwalb M.G.
Affiliations
1 The University of Liverpool
2 Unichema International

Funding (1)

1 Unichema International

Abstract: The peroxo phosphotungstate {PO4[WO(O2)2]4}3− is a highly efficient catalyst (or catalyst precursor) for the phase-transfer epoxidation of oleic acid by aqueous 35–60% hydrogen peroxide, yielding 84% epoxide (based on oleic acid) at 95% oleic acid conversion and 800–1200 catalyst turnovers, without using a chlorocarbon solvent.
Cite: Kozhevnikov I.V. , Mulder G.P. , Steverink-de Zoete M.C. , Oostwalb M.G.
Epoxidation of Oleic Acid Catalyzed by Peroxo Phosphotungstate in a Two-Phase System
Journal of Molecular Catalysis A: Chemical. 1998. V.134. N1-3. P.223-228. DOI: 10.1016/S1381-1169(98)00039-9 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Aug 26, 1997
Accepted: Sep 22, 1997
Published print: Sep 15, 1998
Published online: Jan 6, 1999
Identifiers:
publication_identifier.wos_identifier_type WOS:000075960100020
publication_identifier.scopus_identifier_type 2-s2.0-0032530509
publication_identifier.rinz_identifier_type 22010468
publication_identifier.accession_number_identifier_type 1998:533798
publication_identifier.chemical_accession_number_identifier_type 130:3478
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