Preparation of HKUST-1@Silica Aerogel Composite for Continuous Flow Catalysis
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Journal of Sol-Gel Science and Technology
ISSN: 0928-0707
, E-ISSN: 1573-4846
|
| Output data |
Year: 2017,
Volume: 84,
Number: 3,
Pages: 446-452
Pages count
: 7
DOI:
10.1007/s10971-017-4455-3
|
| Tags |
Aerogel pellets, Emulsion, Flow catalysis, HKUST-1, MOF-aerogel composite |
| Authors |
Shalygin Anton S.
1
,
Nuzhdin Alexey L.
1
,
Bukhtiyarova Galina A.
1
,
Martyanov Oleg N.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
|
|
Funding (1)
|
1
|
Federal Agency for Scientific Organizations
|
0303-2015-0009
|
HKUST-1@silica aerogel composite pellets (HKUST-1@SiO2) were prepared by the coupled sol–gel and water-in-oil emulsion method using supercritical CO2 drying. The structure and morphology of HKUST-1@SiO2 were characterized by X-Ray diffraction, scanning electron microscopy and low-temperature nitrogen adsorption. According to these data, the composite represents physically dispersed micron-sized domains of HKUST-1 in the silica aerogel pellets. It was shown that the HKUST-1@SiO2 pellets can be used as a catalyst for isomerization of styrene oxide to phenyl acetaldehyde in a continuous flow reactor.