Catalytic Synthesis of Dialkyl Sulfides from Dialkyl Disulfides Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2017, Volume: 58, Number: 4, Pages: 402-408 Pages count : 7 DOI: 10.1134/S0023158417040115 | ||
Tags | alkanethiols, catalysts, dialkyl disulfides, dialkyl sulfides | ||
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Abstract:
Dialkyl disulfides R2S2 where R = Me, Et, or Pr, both as individual compounds and as their mixtures, isolated from petroleum products can turn into alkanethiols and dialkyl sulfides under the action of catalysts having strong acid sites and medium-strength basic sites on their surface. In a helium atmosphere, the main conversion products are alkanethiols, while dialkyl sulfides form in low yield at a selectivity of no higher than 20%. A much higher dialkyl sulfide selectivity is attained in the reaction involving methanol. The most efficient catalyst for this reaction is alumina, with which the dialkyl sulfide selectivity is up to 99%.
Cite:
Mashkina A.V.
, Khairulina L.N.
Catalytic Synthesis of Dialkyl Sulfides from Dialkyl Disulfides
Kinetics and Catalysis. 2017. V.58. N4. P.402-408. DOI: 10.1134/S0023158417040115 WOS Scopus РИНЦ
Catalytic Synthesis of Dialkyl Sulfides from Dialkyl Disulfides
Kinetics and Catalysis. 2017. V.58. N4. P.402-408. DOI: 10.1134/S0023158417040115 WOS Scopus РИНЦ
Original:
Машкина А.В.
, Хайрулина Л.Н.
Каталитический синтез диалкилсульфидов на основе диалкилдисульфидов
Кинетика и катализ. 2017. Т.58. №4. С.420-427. DOI: 10.7868/S0453881117040128 РИНЦ
Каталитический синтез диалкилсульфидов на основе диалкилдисульфидов
Кинетика и катализ. 2017. Т.58. №4. С.420-427. DOI: 10.7868/S0453881117040128 РИНЦ
Dates:
Submitted: | Dec 27, 2016 |
Published print: | Jul 1, 2017 |
Published online: | Aug 2, 2017 |
Identifiers:
Web of science | WOS:000407057400009 |
Scopus | 2-s2.0-85026776508 |
Elibrary | 31059356 |
Chemical Abstracts | 2017:1262859 |
Chemical Abstracts (print) | 167:586791 |
OpenAlex | W2740210582 |
Citing:
DB | Citing |
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Elibrary | 1 |