Energy of Oxygen Bonding and Catalytic Activity of Certain Oxides Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1969, Volume: 10, Number: 4-1, Pages: 643-650 Pages count : 8 | ||
Tags | Catalysts; KICAA | ||
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Abstract:
Determination has been made of the catalytic activity in isotopic oxygen exchange and hydrogen oxidation of oxides having similar values of the heat of formation (Co3O4, PbO red, PbO yellow, CdO, Bi2O3, Sb2O5). It was found that the activities of these oxides are rather radically different. The heats of formation of these oxides from the elements were compared with the energies of bonding of surface oxygen, as determined from the temperature dependence of the pressure of oxygen above the oxides, to show that the bonding energy is a fraction of the heat of formation, this fraction varying from oxide oxide. catalytic activity has been correlated with the energy of oxygen bonding to the oxide surface.
Cite:
Popovskii V.V.
, Boreskov G.K.
, Muzykantov V.S.
, Sazonov V.A.
, Shubnikov S.G.
Energy of Oxygen Bonding and Catalytic Activity of Certain Oxides
Kinetics and Catalysis. 1969. V.10. N4-1. P.643-650. Scopus РИНЦ
Energy of Oxygen Bonding and Catalytic Activity of Certain Oxides
Kinetics and Catalysis. 1969. V.10. N4-1. P.643-650. Scopus РИНЦ
Original:
Поповский В.В.
, Боресков Г.К.
, Музыкантов В.С.
, Сазонов В.А.
, Шубников С.Г.
Энергия связи кислорода и каталитическая активность некоторых окислов
Кинетика и катализ. 1969. Т.10. №4. С.786-795. РИНЦ
Энергия связи кислорода и каталитическая активность некоторых окислов
Кинетика и катализ. 1969. Т.10. №4. С.786-795. РИНЦ
Dates:
Published print: | Jul 1, 1969 |
Identifiers:
Scopus | 2-s2.0-0014533678 |
Elibrary | 30610342 |