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Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Output data Year: 2005, Volume: 279, Pages: 99-107 Pages count : 9 DOI: 10.1016/j.apcata.2004.10.017
Tags Cis-trans isomerization, Kinetics, Partial hydrogenation, Pd/MgO
Authors Deliy I.V. 1 , Maksimchuk N.V. 1 , Psaro R. 2 , Ravasio N. 2 , Dal Santo V. 2 , Recchia S. 3 , Paukshtis E.A. 1 , Golovin A.V. 1 , Semikolenov V.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Homogeneous and Coordination Catalysis, Novosibirsk 630090, Russia
2 ISTM-CNR, Via C. Golgi, 19-20133 Milano, Italy
3 Dipartimento di Scienze Chimiche, Fisiche e Matematiche, Universita` dell’Insubria-Sede di Como, Via Lucini, 3-22100 Como, Italy

Funding (2)

1 Civilian Research and Development Foundation NO-008-X1
2 Президиум РАН 9

Abstract: Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were studied. Liquid phase hydrogenation was carried out in temperature range of 303–323 K and under hydrogen pressure within 1–10 bar. Gas–liquid chromatography, IR and 13C NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure and reaction temperature on cis and trans methyl oleate formation were studied. The general kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis–trans methyl oleate isomerization have been proposed.
Cite: Deliy I.V. , Maksimchuk N.V. , Psaro R. , Ravasio N. , Dal Santo V. , Recchia S. , Paukshtis E.A. , Golovin A.V. , Semikolenov V.A.
Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO
Applied Catalysis A: General. 2005. V.279. P.99-107. DOI: 10.1016/j.apcata.2004.10.017 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Jul 14, 2004
Accepted: Oct 15, 2004
Published online: Nov 25, 2004
Published print: Jan 28, 2005
Identifiers:
publication_identifier.wos_identifier_type WOS:000226759300010
publication_identifier.scopus_identifier_type 2-s2.0-11944253554
publication_identifier.rinz_identifier_type 13494703
publication_identifier.accession_number_identifier_type 2005:45681
publication_identifier.chemical_accession_number_identifier_type 142:299800
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