Examination of Complexing of Vanadium(v) During Extraction with N-(2-Hydroxy-5-Nonylbenzyl)-β, β-Dihydroxyethylamine Full article
Journal |
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current)
ISSN: 1563-5325 , E-ISSN: 1042-6507 |
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Output data | Year: 2018, Volume: 193, Number: 6, Pages: 382-386 Pages count : 5 DOI: 10.1080/10426507.2018.1424160 | ||||||
Tags | Extraction; vanadium; cyclic tetramer; ionization energy; chelate complex | ||||||
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Abstract:
Extraction of vanadium(V) with the phenol-type tertiary amine N-(2-hydroxy-5-nonylbenzyl)-β,β-dihydroxyethylamine (NBEA) has been examined. The optimal extraction conditions have been determined. It was established that the extracted complex includes the cyclic tetramer V4O12 4− and four molecules The bands observed in the electronic spectra of the extracts are indicative of the formation of a chelate complex of vanadium(V) with N-(2-hydroxy-5-nonylbenzyl)-β,β-dihydroxyethylamine. The V-O bond in the extracted complex is formed owing to the dissociation of a proton from the phenol group, and the V-N bond is due to a lone-electron pair of nitrogen atom of the extractant. The chelate complex formed during the extraction of vanadium(V) with N-(2-hydroxy-5-nonylbenzyl)-β,β-dihydroxyethylamine is stable for more than a month and is not apt to reduction.
Cite:
Kurbatova L.
, Koryakova O.
, Valova M.
, Medvedeva N.
, Maksimovskaya R.
, Ganebnykh I.
Examination of Complexing of Vanadium(v) During Extraction with N-(2-Hydroxy-5-Nonylbenzyl)-β, β-Dihydroxyethylamine
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2018. V.193. N6. P.382-386. DOI: 10.1080/10426507.2018.1424160 WOS Scopus РИНЦ
Examination of Complexing of Vanadium(v) During Extraction with N-(2-Hydroxy-5-Nonylbenzyl)-β, β-Dihydroxyethylamine
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2018. V.193. N6. P.382-386. DOI: 10.1080/10426507.2018.1424160 WOS Scopus РИНЦ
Dates:
Submitted: | Sep 14, 2017 |
Accepted: | Jan 2, 2018 |
Published online: | Feb 23, 2018 |
Published print: | Jun 3, 2018 |
Identifiers:
Web of science | WOS:000433549300007 |
Scopus | 2-s2.0-85042414913 |
Elibrary | 41790273 |
Chemical Abstracts | 2018:336338 |
OpenAlex | W2783727363 |