One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts
Conference Abstracts
| Общее |
Language:
Английский,
Genre:
Conference Abstracts,
Status:
Published,
Source type:
Original
|
| Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015
,
Казань
|
| Source |
EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation,
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
publication_identifier_short.rinz_identifier_type
|
| Output data |
Year: 2015,
Pages: 1693-1694
Pages count
: 2
|
| Authors |
Demidova Yu.S.
1,2
,
Simakova I.L.
1,2
,
Beloshapkin S.
3
,
Warna J.
4
,
Suslov E.V.
5
,
Volcho K.P.
5
,
Salakhutdinov N.F.
5
,
Simakov A.V.
6
,
Murzin D.Y.
4
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Novosibirsk, Russia
|
| 2 |
Novosibirsk State University, Novosibirsk, Russia
|
| 3 |
Materials & Surface Science Institute, University of Limerick, Limerick, Ireland
|
| 4 |
Åbo Akademi University, Turku/Åbo, Finland
|
| 5 |
Novosibirsk Institute of Organic Chemistry, Novosibirsk, Russia
|
| 6 |
Centro de Nanociencias y Nanotecnología, UNAM, Ensenada, México
|
|
The one-pot terpene alcohol amination, which is of high practical importance for the synthesis of complicated amines with specific physiological properties, was systematically studied in the presence of gold catalysts to obtain the knowledge about the key parameters determining the catalytic performance. The catalytic activity and product distribution were shown to be strongly dependent on the support properties, namely acidity and basicity, and conditions of the catalysts pretreatment. The Au/ZrO2 catalyst pretreated under oxidizing atmosphere was observed to be rather active resulting in total conversion of myrtenol and selectivity to corresponding amine of about 53%. The reaction kinetics was modeled based on mechanistic considerations with the catalyst deactivation step included in the mechanism.