Study on Kinetics of Liquid Phase Photocatalytic Oxidation of Dibutyl Sulfide over Fullerenes Conference Abstracts
Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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Source | EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts Compilation, Boreskov Institute of Catalysis. Novosibirsk.2015. 2184 c. ISBN 9785906376107. РИНЦ |
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Output data | Year: 2015, Pages: 2117-2118 Pages count : 2 | ||||
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Funding (2)
1 | Federal Agency for Scientific Organizations | V.45.3.7. |
2 | Russian Foundation for Basic Research | 15-08-01936 |
Abstract:
Fullerenes represent a relatively new allotropic modification of carbon that was discovered in 1985 by Kroto et al. after vaporization of carbon species from the surface of a solid disk of graphite using a focused pulsed laser. The discovery made a revolution in molecular design and it leads to obtaining other novel structures such as graphene and carbon nanotubes. Afterwards photochemical reactivity of fullerene was proved: quantum yield of singlet oxygen production in toluene solution of fullerene C60 is almost 100%. Photoexcited fullerene transfers electron leading to generation reduced oxygen species (O2-• and •OH). Information on photocatalytic activity of fullerenes is available in the literature. However, kinetic studies were never undertaken. In the present work, the influence of several parameters on the rate and selectivity of dibutyl sulfide (DBS) photooxidation on C70 is investigated.
Cite:
Arsentyev A.V.
, Vorontsov A.V.
Study on Kinetics of Liquid Phase Photocatalytic Oxidation of Dibutyl Sulfide over Fullerenes
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.2117-2118. – ISBN 9785906376107.
Study on Kinetics of Liquid Phase Photocatalytic Oxidation of Dibutyl Sulfide over Fullerenes
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.2117-2118. – ISBN 9785906376107.
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