High Temperature N2O Decomposition over Massive and Supported Mixed Oxides: Principles of Activity Regulation
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015
||EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
Novosibirsk State University, Novosibirsk, Russia
Correlation between activity of massive and supported La(-Sr)-Fe and CeO2 based mixed oxides in the reaction of hightemperature N2O decomposition and their capability to supply oxygen from the near subsurface layers to adsorbed species formed after N2O decomposition on the active surface sites was analyzed. Formation of heterostructured interfaces on the surface of intergrown composites or mixed solutions enriched by oxygen vacancies was shown to promote oxygen exchange in the surface and near subsurface layers thus hastening O2 desorption.