Synthesis and Study of Self-Organization of Organo-Inorganic Nanostructures Based on Cationic Poly(meth)acrylates and Molybdenum Disulfide Single Layers Full article
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Polymer Science Series B
ISSN: 1560-0904 , E-ISSN: 1531-8583 |
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Output data | Year: 2013, Volume: 55, Number: 1-2, Pages: 95-106 Pages count : 12 DOI: 10.1134/S1560090413020024 | ||||
Tags | Block Copolymer; Polymer Science Series; ATRP; Molybdenum Disulfide; High Resolution Transmission Electron Microscopy | ||||
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Abstract:
Poly(meth)acrylates of three types, namely, regular homopolymers containing side-chain tetraalkylammonium ionic groups with alkyl radicals of various lengths (C6 and C16), a copolymer with statistically distributed ionic and long-chain (C18) alkyl groups, and a block copolymer of the same composition in which alkylammonium and alkyl groups are located in separate blocks, are synthesized with the use of controlled radical polymerization processes. The interaction of the polymers with molybdenum disulfide singlelayer dispersions yields self-organized organic-inorganic nanocomposites containing up to 40% polymer. As evidenced by powder X-ray diffraction and high-resolution transmission electron microscopy structural studies of the composites, they possess a crystalline layered structure with interlayer distances depending on the composition and structure of the polymer. Structures with the most regular alternation of organic and inorganic layers are formed in the case of homopolymers. The orientation of their alkylammonium fragments relative to MoS2 layers depends on the length of the alkyl radical and corresponds to their parallel (C6) or perpendicular (C16) arrangement.
Cite:
Kabachii Y.A.
, Kochev S.Y.
, Lenenko N.D.
, Zaikovskii V.I.
, Golub A.S.
, Antipin M.Y.
, Valetskii P.M.
Synthesis and Study of Self-Organization of Organo-Inorganic Nanostructures Based on Cationic Poly(meth)acrylates and Molybdenum Disulfide Single Layers
Polymer Science Series B. 2013. V.55. N1-2. P.95-106. DOI: 10.1134/S1560090413020024 WOS Scopus РИНЦ
Synthesis and Study of Self-Organization of Organo-Inorganic Nanostructures Based on Cationic Poly(meth)acrylates and Molybdenum Disulfide Single Layers
Polymer Science Series B. 2013. V.55. N1-2. P.95-106. DOI: 10.1134/S1560090413020024 WOS Scopus РИНЦ
Original:
Кабачий Ю.А.
, Кочев С.Ю.
, Лененко Н.Д.
, Зайковский В.И.
, Голубь А.С.
, Антипин М.Ю.
, Валецкий П.М.
Синтез и изучение закономерностей самоорганизации органо-неорганических наноструктур на основе катионных поли(мет)акрилатов и монослоев дисульфида молибдена
Высокомолекулярные соединения. Серия Б. 2013. Т.55. №2. С.243-254. DOI: 10.7868/S0507547513020062 РИНЦ
Синтез и изучение закономерностей самоорганизации органо-неорганических наноструктур на основе катионных поли(мет)акрилатов и монослоев дисульфида молибдена
Высокомолекулярные соединения. Серия Б. 2013. Т.55. №2. С.243-254. DOI: 10.7868/S0507547513020062 РИНЦ
Dates:
Submitted: | Mar 19, 2012 |
Published print: | Jan 1, 2013 |
Published online: | Feb 20, 2013 |
Identifiers:
Web of science | WOS:000315278100013 |
Scopus | 2-s2.0-84874101128 |
Elibrary | 20434801 |
Chemical Abstracts | 2013:292803 |
Chemical Abstracts (print) | 159:166212 |
OpenAlex | W1976326669 |