Palladium-Promoted Co-SiO2 Catalysts for 1,4-Butanediol Cyclization Full article
Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Output data | Year: 2009, Volume: 362, Number: 1-2, Pages: 147-154 Pages count : 7 DOI: 10.1016/j.apcata.2009.04.033 | ||||||||
Tags | 1,4-Butanediol, 2,3-Dihydrofuran, Cobalt-palladium-silica catalysts, Tetrahydrofuran | ||||||||
Authors |
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Affiliations |
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Funding (1)
1 | European Commission | 2004/0001/VPD1/ESF/PIAA/04/NP/3.2.3.1/0001/0063 |
Abstract:
The conversion of 1,4-butanediol to 2,3-dihydrofuran and tetrahydrofuran over Co–SiO2 and Co,Pd–SiO2 catalysts with 0.09, 0.46, 0.90 and 1.90 wt.% Pd have been investigated in a liquid phase. The Co loading was 40 wt.%. The catalysts were prepared by mechanochemical techniques and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and temperature-programmed reduction (TPR) methods. The catalysts with 0.46 and 0.90% Pd were the best for the 1,4-butanediol cyclization. Palladium decreases the reduction temperature of cobalt phase by 165–185 °C down to 240–260 °C optimum concerning the yield of 2,3-dihydrofuran. It was found by XPS method that an optimum in the degree of cobalt reduction for the reaction of 1,4-butanediol cyclization exists in the region 7–12%. The comparison of nominal catalysts composition and XPS data suggests surface enrichment with palladium after reduction.
Cite:
Stonkus V.
, Edolfa K.
, Leite L.
, Sobczak J.W.
, Plyasova L.
, Petrova P.
Palladium-Promoted Co-SiO2 Catalysts for 1,4-Butanediol Cyclization
Applied Catalysis A: General. 2009. V.362. N1-2. P.147-154. DOI: 10.1016/j.apcata.2009.04.033 WOS Scopus РИНЦ
Palladium-Promoted Co-SiO2 Catalysts for 1,4-Butanediol Cyclization
Applied Catalysis A: General. 2009. V.362. N1-2. P.147-154. DOI: 10.1016/j.apcata.2009.04.033 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 21, 2009 |
Accepted: | Apr 18, 2009 |
Published online: | Apr 24, 2009 |
Published print: | Jun 30, 2009 |
Identifiers:
Web of science | WOS:000267676000021 |
Scopus | 2-s2.0-66149119023 |
Elibrary | 13610604 |
Chemical Abstracts | 2009:662431 |
Chemical Abstracts (print) | 151:176004 |
OpenAlex | W2037971303 |