In situ EPR Study of Chemoselective Hydrogenation of Nitroarenes on Au/Al2O3 Catalyst
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Mendeleev Communications
ISSN: 0959-9436
, E-ISSN: 1364-551X
|
| Output data |
Year: 2018,
Volume: 28,
Number: 5,
Pages: 536–537
Pages count
: 2
DOI:
10.1016/j.mencom.2018.09.029
|
| Tags |
LIQUID-PHASE HYDROGENATION; P-CHLORONITROBENZENE; FLOW REACTOR; SUPPORT; GOLD |
| Authors |
Yakushkin Pavel E.
1
,
Nuzhdin Alexey L.
1
,
Artiukha Ekaterina A.
1
,
Plyusnin Pavel E.
2
,
Bukhtiyarova Galina A.
1
,
Martyanov Oleg N.
1
|
| Affiliations |
| 1 |
G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,
630090 Novosibirsk, Russian Federation
|
| 2 |
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
630090 Novosibirsk, Russian Federation
|
|
Funding (1)
|
1
|
Federal Agency for Scientific Organizations
|
0303-2016-0006 (V.44.1.6)
|
Detected by the in situ EPR spectroscopy immobilized nitro radical anions generated in the course of Au/Al2O3-catalyzed nitrobenzene hydrogenation demonstrate the abnormal hyper-fine splitting and serve as intermediates of the reaction.