Prospect of Using Nanoalloys of Partly Miscible Rhodium and Palladium in Three-Way Catalysis
Science article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Conference |
Eleventh International Congress on Catalysis and Automotive Pollution Control
29-31 Oct 2018
,
Brussels
|
| Journal |
Topics in Catalysis
ISSN: 1022-5528
, E-ISSN: 1572-9028
|
| Output data |
Year: 2019,
Volume: 62,
Number: 1-4,
Pages: 305-314 SI
Pages count
: 10
DOI:
10.1007/s11244-018-1093-0
|
| Tags |
Partly miscible metals; Pd-Rh alloy; Double complex salt; CO oxidation; Prompt thermal aging |
| Authors |
Vedyagin Aleksey A.
1,2
,
Shubin Yury V.
3,4
,
Kenzhin Roman M.
1
,
Plyusnin Pavel E.
3,4
,
Stoyanovskii Vladimir O.
1
,
Volodin Alexander M.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS Novosibirsk Russian Federation
|
| 2 |
National Research Tomsk Polytechnic University Tomsk Russian Federation
|
| 3 |
Nikolaev Institute of Inorganic Chemistry SB RAS Novosibirsk Russian Federation
|
| 4 |
National Research University – Novosibirsk State University Novosibirsk Russian Federation
|
|
Funding (1)
|
1
|
The Ministry of Education and Science of the Russian Federation
|
14.581.21.0028 (RFMEFI58117X0028)
|
Alloys of partly miscible metals attract a growing attention due to their unique physicochemical properties. Palladium-rhodium solid solution was synthesized using a multi-metal single precursor concept. Pd-Rh/γ-Al2O3 catalyst was prepared by an impregnation of the support with a solution of a precursor containing organic ligand. The Pd:Rh ratio in the alloy was 3:2. The samples were characterized by a powder X-ray diffraction analysis, a transmission electron microscopy, electron paramagnetic resonance and photoluminescence spectroscopies. The catalytic behavior of the samples was examined in CO oxidation reaction under prompt thermal aging conditions. The stability of the bimetallic catalyst was found to be improved if compare with monometallic reference samples. Mutual anchoring of palladium and rhodium prevents both the surface migration of Pd particles followed by their agglomeration and the diffusion of rhodium ions into the bulk of alumina support. Improved metal-support interaction for the studied system was found to be facilitated by presence of electron donor sites on the surface of the support.