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Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2016, Volume: 65, Number: 11, Pages: 2712-2717 Pages count : 6 DOI: 10.1007/s11172-016-1640-4
Tags polyvinyl chloride, carbon materials, conjugated polymers, polyvinylenes, waste recycling.
Authors Solodovnichenko V.S. 1,2 , Kryazhev Yu.G. 1,2 , Arbuzov A.B. 2 , Talzi V.P. 2 , Antonicheva N.V. 1,2 , Drozdov V.A. 1,2 , Zapevalova E.S. 2 , Likholobov V.A. 1,2
Affiliations
1 Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences, 15 prosp. Marksa, 644024 Omsk, Russian Federation
2 Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences, 54 ul. Neftezavodskaya, 644040 Omsk, Russian Federation

Funding (1)

1 Russian Science Foundation 14-33-00018 (114123040010)

Abstract: A method for carbon materials synthesis based on polyvinyl chloride has been proposed. Method includes polymer dehydrochlorination by alkali with carbonrich conjugated structures (polyvinylenes) formation and its subsequent carbonization at relatively low temperatures. Raman and 13C NMR spectroscopy and transmission electron microscopy show that thermal treatment of the resulting polyvinylenes up to 400 °C leads to the formation of amorphous carbon material with chlorine contain less than 0.5 wt.%. These results can be used to develop dioxinfree technology of utilization of polyvinyl chloride and its wastes.
Cite: Solodovnichenko V.S. , Kryazhev Y.G. , Arbuzov A.B. , Talzi V.P. , Antonicheva N.V. , Drozdov V.A. , Zapevalova E.S. , Likholobov V.A.
Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials
Russian Chemical Bulletin. 2016. V.65. N11. P.2712-2717. DOI: 10.1007/s11172-016-1640-4 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Солодовниченко В.С. , Кряжев Ю.Г. , Арбузов А.Б. , Талзи В.П. , Антоничева Н.В. , Дроздов В.А. , Запевалова Е.С. , Лихолобов В.А.
Поливинилхлорид как предшественник для низкотемпературного синтеза углеродных материалов
Известия Академии наук. Серия химическая. 2016. №11. С.2712-2717. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: May 25, 2016
Accepted: Aug 15, 2016
Published print: Nov 1, 2016
Published online: May 17, 2017
Identifiers:
publication_identifier.wos_identifier_type WOS:000401572700023
publication_identifier.scopus_identifier_type 2-s2.0-85019199718
publication_identifier.rinz_identifier_type 31027609
publication_identifier.accession_number_identifier_type 2017:802414
publication_identifier.chemical_accession_number_identifier_type 167:6329
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