Structural and Morphological Transformations of Carbon Nanospheres during High-Temperature, High-Pressure Processing
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
Journal |
Inorganic Materials
ISSN: 0020-1685
, E-ISSN: 1608-3172
|
Output data |
Year: 2017,
Volume: 53,
Number: 5,
Pages: 462-468
Pages count
: 7
DOI:
10.1134/s0020168517050065
|
Tags |
turbostratic carbon spheres, high pressures, graphite, diamond |
Authors |
Filonenko V.P.
1
,
Zibrov I.P.
1
,
Trenikhin M.V.
2,3
,
Pavlyuchenko P.E.
2,3
,
Arbuzov A.B.
2,3
,
Drozdov V.A.
2,3
,
Likholobov V.A.
2,3
|
Affiliations |
1 |
Vereshchagin Institute of High-Pressure Physics, Russian Academy of Sciences,
Kaluzhskoe sh. 14, Troitsk, Moscow, 108840 Russia
|
2 |
Institute of Hydrocarbon Processing Problems, Siberian Branch, Russian Academy of Sciences,
Neftezavodskaya ul. 54, Omsk, 644040 Russia
|
3 |
Omsk Scientific Center, Siberian Branch, Russian Academy of Sciences, pr. Karla Marksa 15, Omsk, 644040 Russia
|
|
Funding (1)
1
|
Russian Foundation for Basic Research
|
15-03-04490
|
This paper presents analysis of structural changes in powders consisting of turbostratic carbon spheres with an average particle diameter of 250 and 25 nm after high-temperature, high-pressure processing at a pressure of 8 GPa. It has been shown that marked ordering of graphene sheets is observed at 1300°C and actively proceeds at higher temperatures. The major morphological species in the samples after processing is slabs of graphene sheets, and three-dimensional structural perfection is higher at the smaller particle size. Using high-resolution electron microscopy, samples of this powder were shown to contain diamond nanocrystallites.