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Palladium Nanoparticles Supported on Carbon Nanoglobules as Efficient Catalysts for Obtaining Benzocaine via Selective Hydrogenation of Ethyl 4-Nitrobenzoate Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Output data Year: 2018, Volume: 114, Pages: 46-50 Pages count : 5 DOI: 10.1016/j.catcom.2018.06.002
Tags Catalytic hydrogenation; Carbon nanoglobules; Palladium catalysts; Ethyl 4-nitrobenzoate; Benzocaine
Authors Mironenko Roman M. 1,2 , Belskaya Olga B. 1,3 , Gulyaeva Tatiana I. 1 , Trenikhin Mikhail V. 1,3 , Likholobov Vladimir A. 1,4
Affiliations
1 Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, 54 Neftezavodskaya st., 644040, Omsk, Russia
2 Dostoevsky Omsk State University, 55a Mira ave., 644077, Omsk, Russia
3 Omsk State Technical University, 11 Mira ave., 644050, Omsk, Russia
4 Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, 15 Karla Marksa ave., 644024, Omsk, Russia

Funding (1)

1 Russian Foundation for Basic Research 16-29-10742

Abstract: The palladium catalysts prepared using carbon nanoglobules (CNGs) as the support and containing no more than 2 wt% Pd were shown to be highly effective for the liquid-phase hydrogenation of ethyl 4-nitrobenzoate under mild conditions. Regardless of the kind of CNGs and the catalyst preparation method, the most of the Pd/CNGs catalysts allow achieving a complete conversion of substrate giving benzocaine in a 100% yield. The Pd/CNGs catalyst is easily recycled many times without loss of its catalytic performance. The results obtained may be useful for the development of effective Pd/C catalysts for chemoselective hydrogenation of various nitroarenes.
Cite: Mironenko R.M. , Belskaya O.B. , Gulyaeva T.I. , Trenikhin M.V. , Likholobov V.A.
Palladium Nanoparticles Supported on Carbon Nanoglobules as Efficient Catalysts for Obtaining Benzocaine via Selective Hydrogenation of Ethyl 4-Nitrobenzoate
Catalysis Communications. 2018. V.114. P.46-50. DOI: 10.1016/j.catcom.2018.06.002 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Apr 27, 2018
Accepted: Jun 1, 2018
Published online: Jun 6, 2018
Published print: Aug 1, 2018
Identifiers:
publication_identifier.wos_identifier_type WOS:000440771300011
publication_identifier.scopus_identifier_type 2-s2.0-85048274044
publication_identifier.rinz_identifier_type 35668721
publication_identifier.accession_number_identifier_type 2018:1112294
publication_identifier.chemical_accession_number_identifier_type 171:268265
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