Dry Reforming of Methane over Fluorite-Like Mixed Oxides Promoted by Pt Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 2009, Volume: 98, Number: 1, Pages: 35-41 Pages count : 7 DOI: 10.1007/s11144-009-0064-7 | ||||||
Tags | Flow system, Methane dry reforming, Short contact time, Syngas | ||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 09-03-93112 |
2 | Russian Foundation for Basic Research | 05-03-34761 |
Abstract:
Dry reforming of methane into syngas was studied over complex Pt-promoted fluorite-like oxides (PrCeZrO, GdCeZrO and LaCeZrO) supported on a corundum substrate. Activity and syngas selectivity of these catalysts were found to depend strongly on their composition, pretreatment and reaction conditions. At low temperatures and short contact times, the H2/CO ratio in the syngas is below 1 due to a fast reverse water–gas shift reaction. The catalyst performance was found to correlate with the bulk oxygen mobility in complex fluorite-like oxides, which prevents the surface coking.
Cite:
Sazonova N.N.
, Sadykov V.A.
, Bobin A.S.
, Pokrovskaya S.A.
, Gubanova E.L.
, Mirodatos C.
Dry Reforming of Methane over Fluorite-Like Mixed Oxides Promoted by Pt
Reaction Kinetics and Catalysis Letters. 2009. V.98. N1. P.35-41. DOI: 10.1007/s11144-009-0064-7 WOS Scopus РИНЦ
Dry Reforming of Methane over Fluorite-Like Mixed Oxides Promoted by Pt
Reaction Kinetics and Catalysis Letters. 2009. V.98. N1. P.35-41. DOI: 10.1007/s11144-009-0064-7 WOS Scopus РИНЦ
Dates:
Submitted: | Dec 18, 2008 |
Accepted: | Jul 20, 2009 |
Published online: | Sep 11, 2009 |
Published print: | Oct 1, 2009 |
Identifiers:
Web of science | WOS:000270190100005 |
Scopus | 2-s2.0-70349508964 |
Elibrary | 15306673 |
Chemical Abstracts | 2009:1184526 |
Chemical Abstracts (print) | 153:534179 |
OpenAlex | W1994193130 |