Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285
, E-ISSN: 1573-9171
|
| Output data |
Year: 2009,
Volume: 58,
Number: 1,
Pages: 134-137
Pages count
: 4
DOI:
10.1007/s11172-009-0020-8
|
| Tags |
Catalysis, Hydrogen peroxide, Liquid-phase oxidation, Organic sulfides, Polyoxomolybdates, Tert-butyl hydroperoxide |
| Authors |
Izarova N.V.
1
,
Kholdeeva O.A.
2
,
Sokolov M.N.
1,3
,
Fedin V.P.
1,3
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS
|
| 2 |
Boreskov Institute of Catalysis SB RAS
|
| 3 |
Novosibirsk State University
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
06-03-32831
|
The catalytic properties of the iron-containing Keplerate [H4Mo72Fe30O254(CH3COO)10-Mo2O7(H2O)H2Mo2O8(H2O)3(H2O)87] • (~80)H2O (1) in the selective liquid-phase oxidation of thio ethers were studied. Compound 1 shows high catalytic activity and selectivity in the oxidation of organic sulfides to sulfoxides when hydrogen peroxide and tert-butyl hydroperoxide are used as oxidants.