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Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides Full article

Common Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2009, Volume: 58, Number: 1, Pages: 134-137 Pages count : 4 DOI: 10.1007/s11172-009-0020-8
Tags Catalysis, Hydrogen peroxide, Liquid-phase oxidation, Organic sulfides, Polyoxomolybdates, Tert-butyl hydroperoxide
Authors Izarova N.V. 1 , Kholdeeva O.A. 2 , Sokolov M.N. 1,3 , Fedin V.P. 1,3
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS
2 Boreskov Institute of Catalysis SB RAS
3 Novosibirsk National Research University

Funding (1)

1 Russian Foundation for Basic Research 06-03-32831

Abstract: The catalytic properties of the iron-containing Keplerate [H4Mo72Fe30O254(CH3COO)10-Mo2O7(H2O)H2Mo2O8(H2O)3(H2O)87] • (~80)H2O (1) in the selective liquid-phase oxidation of thio ethers were studied. Compound 1 shows high catalytic activity and selectivity in the oxidation of organic sulfides to sulfoxides when hydrogen peroxide and tert-butyl hydroperoxide are used as oxidants.
Cite: Izarova N.V. , Kholdeeva O.A. , Sokolov M.N. , Fedin V.P.
Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides
Russian Chemical Bulletin. 2009. V.58. N1. P.134-137. DOI: 10.1007/s11172-009-0020-8 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Изарова Н.В. , Холдеева О.А. , Соколов М.Н. , Федин В.П.
Исследование каталитических свойств макромолекулярного полиоксомолибдата в реакциях селективного окисления тиоэфиров
Известия Академии наук. Серия химическая. 2009. №1. С.134-137. РИНЦ
Dates:
Submitted: Jan 30, 2008
Published print: Jan 1, 2009
Published online: Mar 2, 2010
Identifiers:
Web of science WOS:000276107500020
Scopus 2-s2.0-77649263302
Elibrary 15306279
AN 2010:257465
CAN 153:358479
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