Ni–Cu and Ni–Co Alloys: Synthesis, Structure, and Catalytic Activity for the Decomposition of Chlorinated Hydrocarbons
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Inorganic Materials
ISSN: 0020-1685
, E-ISSN: 1608-3172
|
| Output data |
Year: 2014,
Volume: 50,
Number: 6,
Pages: 566-571
Pages count
: 6
DOI:
10.1134/S0020168514060156
|
| Authors |
Rudnev A.V.
1
,
Lysakova A.S.
2
,
Plyusnin P.E.
1,3
,
Bauman Yu.I.
4
,
Shubin Yu.V.
1,3
,
Mishakov I.V.
2,4
,
Vedyagin A.A.
2,4
,
Buyanov R.A.
4
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
|
| 2 |
Novosibirsk State Technical University, pr. Marksa 20, Novosibirsk, 630073 Russia
|
| 3 |
Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia
|
| 4 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
|
|
Funding (3)
|
1
|
Russian Foundation for Basic Research
|
14-03-00411
|
|
2
|
Президиум РАН
|
5.2.2
|
|
3
|
Council for Grants of the President of the Russian Federation
|
МК-1934.2013.3
|
Homogeneous NixCu1 – x and NixCo1 – x (x = 0.90–0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of singlephase NixM1 – x alloys in all of the samples has been confirmed by Xray diffraction. We have assessed the catalytic activity of the alloys for 1,2dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26–27 g/gcat) was offered by the nickel alloys containing ~1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.