Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia Full article
Journal |
Catalysis for Sustainable Energy
ISSN: 2084-6819 |
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Output data | Year: 2018, Volume: 5, Number: 1, Pages: 49-58 Pages count : 10 DOI: 10.1515/cse-2018-0007 | ||||||||||
Tags | one-pot alcohol amination, gold, mixed oxides, ceriaalumina, ceria-alumina-zirconia, alumina, terpene alcohol | ||||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 16-33-60028 |
2 | National Autonomous University of Mexico | 117203 |
Abstract:
In the current work gold catalysts supported on both commercial oxides and oxides synthesized by the sol-gel method were used for the one-pot alcohol amination of myrtenol. In general, utilization of metal oxides synthesized by the sol-gel method as the gold catalyst support enhanced the knowledge regarding key parameters determining catalytic behavior. Synthesized alumina was characterized by stronger acid sites favoring primary amine accumulation on the catalyst surface, as compared to the commercial oxide. Utilization of mixed metal oxides synthesized by the sol-gel method resulted in the non-additive behavior of different oxides enhancing the catalytic activity. Introduction of ceria into alumina modified the support basicity resulting in more efficient alcohol activation.
Cite:
Demidova Y.S.
, Simakova I.L.
, Suslov E.V.
, Volcho K.P.
, Salakhutdinov N.F.
, Simakov A.
, Murzin D.Y.
Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia
Catalysis for Sustainable Energy. 2018. V.5. N1. P.49-58. DOI: 10.1515/cse-2018-0007 РИНЦ
Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia
Catalysis for Sustainable Energy. 2018. V.5. N1. P.49-58. DOI: 10.1515/cse-2018-0007 РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Oct 29, 2018 |
Accepted: | Nov 8, 2018 |
Published print: | Dec 1, 2018 |
Published online: | Dec 31, 2018 |
Identifiers:
Elibrary | 44642882 |
Chemical Abstracts | 2019:2274459 |
OpenAlex | W2917806931 |