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On the Feasibility of Bifunctional Hydrogen Oxidation on Ni and NiCu Surfaces Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Electrochimica Acta
ISSN: 0013-4686 , E-ISSN: 1873-3859
Output data Year: 2019, Volume: 305, Pages: 452-458 Pages count : 7 DOI: 10.1016/j.electacta.2019.03.030
Tags Hydrogen oxidation reaction, Nickel and nickel copper, Bifunctional mechanism, DFT and Monte Carlo simulations, Kinetic modeling
Authors Salmazo D. 1,5 , Juarez M.F. 1 , Oshchepkov A.G. 2 , Cherstiouk O.V. 2 , Bonnefont A. 3 , Shermukhamedov S.A. 4 , Nazmutdinov R.R. 4 , Schmickler W. 1 , Savinova E.R. 5
Affiliations
1 Institute of Theoretical Chemistry, Ulm University, D-89069, Ulm, Germany
2 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
3 Institut de Chimie de Strasbourg, UMR 7177, CNRS-University of Strasbourg, 67070, Strasbourg, France
4 Kazan National Research Technological University, 420015, Kazan, Russian Federation
5 ICPEES, UMR 7515, CNRS-University of Strasbourg, 67087, Strasbourg Cedex, France

Funding (3)

1 Russian Foundation for Basic Research 17-53-150008
2 National Scientific and Technical Research Council
3 National Council for Scientific and Technological Development 248817/2013-2

Abstract: Nickel is a promising alternative to noble metal catalysts for hydrogen electrocatalysis in alkaline membrane fuel cells and electrolyzers. To boost its electrocatalytic activity, it is often associated with other metals, like Cu. In this work, we combine density functional theory (DFT), Monte Carlo calculations and kinetic modeling in order to shed light on the origin of the experimentally observed activity enhancement on bimetallic NiCu nanoparticles containing ca. 5% of Cu compared to pure Ni (Topics in Catalysis, 58, (2015), 1181–1192; J. Electroanal. Chem., 783, (2016), 146–151). It is shown that the bifunctional HOR mechanism, where H ad and OH ad recombine to form water, is not viable on the monometallic Ni electrode because of the strong hydrogen adsorption and the high activation energy barrier of the recombination reaction. On bimetallic NiCu surfaces, DFT calculations predict a significant weakening of H ad adsorption energy as well as a decrease of the activation barrier of the recombination reaction for ca. 50% Cu surface coverage. Monte Carlo simulations reveal that the surface of NiCu nanoparticles is enriched in Cu atoms even for a small (ca. 5%) Cu atomic fraction in the bulk. Kinetic modeling suggests that the experimental data for NiCu nanoparticles can be well reproduced either considering fast recombination step (bifunctional mechanism) or fast (10-fold enhancement compared to pure Ni) Volmer step (Heyrovsky-Volmer mechanism). © 2019 Elsevier Ltd
Cite: Salmazo D. , Juarez M.F. , Oshchepkov A.G. , Cherstiouk O.V. , Bonnefont A. , Shermukhamedov S.A. , Nazmutdinov R.R. , Schmickler W. , Savinova E.R.
On the Feasibility of Bifunctional Hydrogen Oxidation on Ni and NiCu Surfaces
Electrochimica Acta. 2019. V.305. P.452-458. DOI: 10.1016/j.electacta.2019.03.030 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Oct 31, 2018
Accepted: Mar 4, 2019
Published online: Mar 7, 2019
Published print: May 10, 2019
Identifiers:
publication_identifier.wos_identifier_type WOS:000462774000049
publication_identifier.scopus_identifier_type 2-s2.0-85063101730
publication_identifier.rinz_identifier_type 38671514
publication_identifier.accession_number_identifier_type 2019:563757
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