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N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2019, Volume: 60, Number: 3, Pages: 343-354 Pages count : 12 DOI: 10.1134/S0023158419030030
Tags activity; copper state; Cu-containing layered double hydroxides; N-methylation; p-anisidine
Authors Bukhtiyarova M.V. 1 , Nuzhdin A.L. 1 , Kardash T.Yu. 1 , Bukhtiyarov A.V. 1 , Gerasimov E.Yu. 1 , Romanenko A.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0004
2 Federal Agency for Scientific Organizations 0303-2016-0006 (V.44.1.6)

Abstract: Cu-containing layered double hydroxides with different Cu : Al ratios are synthesized by co-precipitation using a mixture of hydroxide and sodium carbonate as a precipitation agent. The influence of the precipitation agent concentration on the formation of the hydrotalcite phase was studied by thermal analysis and X-ray diffraction. The surface of the obtained samples after calcination at 450°C and their subsequent reduction at 300°C in hydrogen, was characterized by X-ray photoelectron spectroscopy and transmission electron microscopy. The synthesized catalysts were tested in the reaction of N-methylation of p-anisidine with methanol in an autoclave reactor to produce N-methyl-p-anisidine. The influence of the Cu : Al ratio in them on the catalytic activity and selectivity was studied.
Cite: Bukhtiyarova M.V. , Nuzhdin A.L. , Kardash T.Y. , Bukhtiyarov A.V. , Gerasimov E.Y. , Romanenko A.V.
N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides
Kinetics and Catalysis. 2019. V.60. N3. P.343-354. DOI: 10.1134/S0023158419030030 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Бухтиярова М.С. , Нуждин А.Л. , Кардаш Т.Ю. , Бухтияров А.В. , Герасимов Е.Ю. , Романенко А.В.
N-метилирование пара-анизидина на катализаторах на основе Cu-содержащих слоистых двойных гидроксидов
Кинетика и катализ. 2019. Т.60. №3. С.364-376. DOI: 10.1134/S0453881119030031 publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Sep 4, 2018
Accepted: Jan 15, 2019
Published print: May 1, 2019
Published online: Jun 18, 2019
Identifiers:
publication_identifier.wos_identifier_type WOS:000472087300012
publication_identifier.scopus_identifier_type 2-s2.0-85065440899
publication_identifier.rinz_identifier_type 41622620
publication_identifier.accession_number_identifier_type 2019:1219352
publication_identifier.chemical_accession_number_identifier_type 172:130128
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