Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters Full article
Journal |
Inorganic Chemistry Frontiers
ISSN: 2052-1545 , E-ISSN: 2052-1553 |
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Output data | Year: 2019, Volume: 6, Number: 6, Pages: 1518-1526 Pages count : 9 DOI: 10.1039/c9qi00339h | ||||||||||
Tags | Binary alloys Crystalline materials Erbium alloys Organometallics Praseodymium alloys Rhenium Thermodynamic stability | ||||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2019-0003 |
2 | Russian Foundation for Basic Research | 18-29-04007 (АААА-А18-118070990004-3) |
Abstract:
The octahedral chalcocyanide cluster anion [Re6S8(CN)6]4- can serve as a metallolinker for the self-assembly of metal-organic frameworks (MOFs) comprising polynuclear lanthanide complexes, which have been illustrated for a series of nine compounds isolated as [{Ln4(μ3-OH)4(ina)4(H2O)n}{Re6S8(CN)6}]·mH2O (Ln = Pr-Er, ina = isonicotinate). Their solid-state framework structures are based on {Ln4(μ3-OH)4}8+ cubane fragments interlinked by isonicotinate and rhenium cyanide clusters. The coordination environment of the lanthanide ions, the coordination numbers and even the number of bridging isonicotinate moieties changes systematically within the lanthanide row, however, the framework topology remains unchanged, confirming the structure-directing role of the rhenium cluster. Structures, magnetochemical properties, luminescence and thermal stability of the new MOFs have been thoroughly analyzed. © 2019 the Partner Organisations.
Cite:
Litvinova Y.M.
, Gayfulin Y.M.
, van Leusen J.
, Samsonenko D.G.
, Lazarenko V.A.
, Zubavichus Y.V.
, Kögerler P.
, Mironov Y.V.
Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters
Inorganic Chemistry Frontiers. 2019. V.6. N6. P.1518-1526. DOI: 10.1039/c9qi00339h WOS Scopus РИНЦ
Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters
Inorganic Chemistry Frontiers. 2019. V.6. N6. P.1518-1526. DOI: 10.1039/c9qi00339h WOS Scopus РИНЦ
Dates:
Submitted: | Mar 27, 2019 |
Accepted: | May 6, 2019 |
Published online: | May 6, 2019 |
Published print: | Jun 6, 2019 |
Identifiers:
Web of science | WOS:000472193200021 |
Scopus | 2-s2.0-85067249651 |
Elibrary | 41634880 |
Chemical Abstracts | 2019:884585 |
OpenAlex | W2944352503 |