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Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2019, Volume: 11, Number: 3, Pages: 216-223 Pages count : 8 DOI: 10.1134/s2070050419030103
Tags furfural, furfuryl alcohol, hydrogenation, copper–iron catalysts
Authors Selishcheva S.A. 1,2 , Smirnov A.A. 1,2 , Fedorov A.V. 1,2 , Ermakov D.Yu. 1 , Gulyaeva Yu.K. 1,2 , Yakovlev V.A. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
2 Novosibirsk State University

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 14.575.21.0171 (RFMEFI57517X0171)

Abstract: Cu- and Fe-containing catalysts are studied in the reaction of selective hydrogenation of furfural to furfuryl alcohol (FA). The catalysts are prepared by alloying the respective metal nitrates and reduced before the reaction directly in the reactor at 250°C. The process is conducted in a batch reactor at 150°C and 6.0 MPa of hydrogen pressure. It is shown that the most active catalyst is Cu20Fe66Al14, the furfural conversion and selectivity toward FA in the presence of which are 96 and 97 mol %, respectively. Inside a continuous-flow reactor in the presence of this catalyst, 100% furfural conversion can be attained at a selectivity toward FA of up to 95 mol % at 160°C and 5 MPa of hydrogen pressure. The resulting catalyst remains active for 30 h of continuous operation. The high activity of the copper–iron catalyst is likely due to the presence of stabilized finely divided copper particles in it.
Cite: Selishcheva S.A. , Smirnov A.A. , Fedorov A.V. , Ermakov D.Y. , Gulyaeva Y.K. , Yakovlev V.A.
Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural
Catalysis in Industry. 2019. V.11. N3. P.216-223. DOI: 10.1134/s2070050419030103 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Селищева С.А. , Смирнов А.А. , Федоров А.В. , Ермаков Д.Ю. , Гуляева Ю.К. , Яковлев В.А.
Получение фурфурилового спирта в присутствии медь-железосодержащих катализаторов в реакции селективного гидрирования фурфурола
Катализ в промышленности. 2019. Т.19. №2. С.95-103. DOI: 10.18412/1816-0387-2019-2-95-103 publication_identifier_short.rsci_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Nov 14, 2018
Accepted: Jan 17, 2019
Published print: Jul 1, 2019
Published online: Sep 16, 2019
Identifiers:
publication_identifier.wos_identifier_type WOS:000486336600005
publication_identifier.scopus_identifier_type 2-s2.0-85073189369
publication_identifier.rinz_identifier_type 41694067
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