Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence Full article
Journal |
European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682 |
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Output data | Year: 2017, Volume: 2017, Number: 35, Pages: 4131-4137 Pages count : 7 DOI: 10.1002/ejic.201700618 | ||||||
Tags | Carboxylate ligands; Cluster compounds; Electrochemistry; Luminescence; Tungsten | ||||||
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Abstract:
The reactions between (Bu4N)2[{W6I8}I6] (1) and silver carboxylates RCOOAg in CH2Cl2 afforded new luminescent carboxylate complexes (Bu4N)2[{W6I8}(RCOO)6] [R = CH3 (2), C6H5 (3), C2F5 (4), C3F7 (5), C6F5 (6)]. The complexes were characterized by single‐crystal X‐ray diffraction, elemental analysis, cyclic voltammetry, and IR and NMR spectroscopy. Complexes 1–6 all exhibit intense and long‐lived photoluminescence. The carboxylate complexes undergo reversible electrochemical oxidation in two consecutive one‐electron steps.
Cite:
Sokolov M.N.
, Brylev K.A.
, Abramov P.A.
, Gallyamov M.R.
, Novozhilov I.N.
, Kitamura N.
, Mikhaylov M.A.
Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence
European Journal of Inorganic Chemistry. 2017. V.2017. N35. P.4131-4137. DOI: 10.1002/ejic.201700618 WOS Scopus РИНЦ
Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence
European Journal of Inorganic Chemistry. 2017. V.2017. N35. P.4131-4137. DOI: 10.1002/ejic.201700618 WOS Scopus РИНЦ
Dates:
Submitted: | May 26, 2017 |
Published online: | Aug 8, 2017 |
Published print: | Sep 25, 2017 |
Identifiers:
Web of science | WOS:000411745000005 |
Scopus | 2-s2.0-85029799099 |
Elibrary | 31057017 |
Chemical Abstracts | 2017:1549178 |
Chemical Abstracts (print) | 167:491943 |
OpenAlex | W2742852371 |