The First Molybdenum Oxo-iodide Cluster - [Mo4OI12]2- Full article
Journal |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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Output data | Year: 2018, Volume: 644, Number: 8-9, Pages: 438-442 Pages count : 5 DOI: 10.1002/zaac.201800053 | ||||||
Tags | Butterfly-type core; Electrochemistry; Molybdenum; Molybdenum iodide cluster; Structure; Synthesis | ||||||
Authors |
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Abstract:
Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster
[Mo4OI12]2–. The structure of tetraphenylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.
Cite:
Mikhaylov M.A.
, Abramov P.A.
, Novozhilov I.N.
, Sokolov M.N.
The First Molybdenum Oxo-iodide Cluster - [Mo4OI12]2-
Zeitschrift fur Anorganische und Allgemeine Chemie. 2018. V.644. N8-9. P.438-442. DOI: 10.1002/zaac.201800053 WOS Scopus РИНЦ
The First Molybdenum Oxo-iodide Cluster - [Mo4OI12]2-
Zeitschrift fur Anorganische und Allgemeine Chemie. 2018. V.644. N8-9. P.438-442. DOI: 10.1002/zaac.201800053 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 13, 2018 |
Published online: | Apr 12, 2018 |
Published print: | May 17, 2018 |
Identifiers:
Web of science | WOS:000439880000005 |
Scopus | 2-s2.0-85054688763 |
Elibrary | 38629582 |
Chemical Abstracts | 2018:802973 |
OpenAlex | W2801001302 |