Efficient Epoxidation of Olefins by H2O2 Catalyzed by Iron “Helmet” Phthalocyanines
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Chemical Communications
ISSN: 1359-7345
, E-ISSN: 1364-548X
|
| Output data |
Year: 2013,
Volume: 49,
Pages: 5577-5579
Pages count
: 3
DOI:
10.1039/c3cc42301h
|
| Authors |
Skobelev Igor Y.
1,2
,
Kudrik Evgeny V.
1,3
,
Zalomaeva Olga V.
2
,
Albrieux Florian
4
,
Afanasiev Pavel
1
,
Kholdeeva Oxana A.
2
,
Sorokin Alexander B.
1
|
| Affiliations |
| 1 |
Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), UMR 5256, CNRS-Universite Lyon 1, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France
|
| 2 |
Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, 630090, Russia
|
| 3 |
Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistryand Technology, 7, av. F. Engels, 153000, Ivanovo, Russia
|
| 4 |
Universite Lyon 1, UMR 5246, Centre Commun de Spectrometrie de Masse, 43 bd du 11 Novembre 1918, 69622 Villeurbanne cedex, France
|
|
Funding (2)
|
1
|
French Embassy in Moscow
|
|
|
2
|
Agence Nationale de la Recherche
|
ANR-08-BLAN-0183-01
|
High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2–2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.