Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst Full article
Journal |
Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041 |
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Output data | Year: 2010, Volume: 29, Number: 20, Pages: 4428-4430 Pages count : 3 DOI: 10.1021/om100729y | ||||
Tags | METALLOCENE POLYOLEFIN CATALYSTS; F-C CONTACTS; OLEFIN POLYMERIZATION; TITANIUM COMPLEXES; ACTIVATION; METHYLALUMINOXANE; POLYETHYLENE; EQUILIBRIA; LIGANDS | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 10-03-91330 |
2 | German Research Foundation | Me 1388/9-1 |
Abstract:
Multinuclear NMR spectroscopic studies of polymerization-active species generated by activation of o-F-substituted and nonsubstituted bis(enolatoimine) titanium complexes with MAO evidence a noncovalent interaction of the o-F moieties with the metal center, which is likely to facilitate living ethylene polymerization via suppression of chain transfer and of β-hydrogen transfer processes.
Cite:
Brylyakov K.P.
, Talsi E.P.
, Möller H.M.
, Baier M.C.
, Mecking S.
Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst
Organometallics. 2010. V.29. N20. P.4428-4430. DOI: 10.1021/om100729y WOS Scopus РИНЦ
Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst
Organometallics. 2010. V.29. N20. P.4428-4430. DOI: 10.1021/om100729y WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Jul 26, 2010 |
Published online: | Sep 27, 2010 |
Published print: | Oct 25, 2010 |
Identifiers:
Web of science | WOS:000282930900005 |
Scopus | 2-s2.0-77958087805 |
Elibrary | 16696308 |
Chemical Abstracts | 2010:1205959 |
Chemical Abstracts (print) | 153:555283 |
OpenAlex | W2061090529 |