Thermal Decomposition of Transition Metal Biphthalates [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) and Copper Biphthalate [Cu(C8H5O4)2(H2O)2]. Synthesis of Metal-Polymer Composites Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Output data | Year: 2010, Volume: 36, Number: 1, Pages: 22-26 Pages count : 5 DOI: 10.1134/S1070328410010033 | ||||
Tags | Phthalate; Coordination Chemistry; Thermolysis; Phthalic Acid; Total Weight Loss | ||||
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Abstract:
The decomposition of transition metal biphthalates [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) and copper biphthalate [Cu(C8H5O4)2(H2O)2] was studied by thermal analysis and mass spectrometry. The decomposition was shown to proceed in three stages: the temperature of the third stage of decomposition decreased in the series of iron, cobalt, nickel, and copper biphthalates from 365 to 275°C. The mass spectrometric study showed the evolution of CO2, diphenylene C12H8, and fluorene (C6H4)2CH2 that at this stage. It was shown by electron scanning microscopy, X-ray diffraction analysis, and chemical analysis that the final thermolysis product of transition metal biphthalates was a composite consisting of the polymer and incorporated into it round submicronic aggregates with metallic particles inside.
Cite:
Yudanova L.I.
, Logvinenko V.A.
, Semyannikov P.P.
, Yudanov N.F.
, Rudina N.A.
Thermal Decomposition of Transition Metal Biphthalates [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) and Copper Biphthalate [Cu(C8H5O4)2(H2O)2]. Synthesis of Metal-Polymer Composites
Russian Journal of Coordination Chemistry. 2010. V.36. N1. P.22-26. DOI: 10.1134/S1070328410010033 WOS Scopus РИНЦ
Thermal Decomposition of Transition Metal Biphthalates [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) and Copper Biphthalate [Cu(C8H5O4)2(H2O)2]. Synthesis of Metal-Polymer Composites
Russian Journal of Coordination Chemistry. 2010. V.36. N1. P.22-26. DOI: 10.1134/S1070328410010033 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Юданова Л.И.
, Логвиненко В.А.
, Семянников П.П.
, Юданов Н.Ф.
, Рудина Н.А.
Изучение термического разложения бифталатов переходных металлов [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) и бифталата меди [Cu(C8H5O4)2(H2O)2]. Синтез композитов металл–полимер
Координационная химия. 2010. Т.36. №1. С.24-28. РИНЦ
Изучение термического разложения бифталатов переходных металлов [M(H2O)6](C8H5O4)2 (M = Fe, Co, Ni) и бифталата меди [Cu(C8H5O4)2(H2O)2]. Синтез композитов металл–полимер
Координационная химия. 2010. Т.36. №1. С.24-28. РИНЦ
Dates:
Submitted: | May 5, 2009 |
Published print: | Jan 1, 2010 |
Published online: | Jan 21, 2010 |
Identifiers:
Web of science | WOS:000273796200003 |
Scopus | 2-s2.0-74849109472 |
Elibrary | 15335407 |
Chemical Abstracts | 2010:80821 |
Chemical Abstracts (print) | 153:348940 |
OpenAlex | W2070382736 |