New Itaconate-Containing Uranyl Complex Unit and Coordination Modes of Itaconate Ions Full article
Journal |
Comptes Rendus Chimie
ISSN: 1631-0748 |
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Output data | Year: 2020, Volume: 23, Number: 2, Pages: 117-126 Pages count : 10 DOI: 10.5802/crchim.8 | ||||||||
Tags | Uranyl, Itaconate, Coordination mode, X-ray diffraction analysis, Voronoi–Dirichlet polyhedra. | ||||||||
Authors |
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Affiliations |
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Funding (3)
1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2019-0003 |
2 | The Ministry of Education and Science of the Russian Federation | 4.5037.2017/8.9 |
3 | The Ministry of Education and Science of the Russian Federation | 0777-2017-0008 |
Abstract:
We performed the synthesis, FTIR spectral study, and X-ray diffraction (XRD) analysis of single crystals of [UO2(C5H4O4)(Dma)] (I), where (C5H4O4)2− and Dma are the itaconate ion and N,N-dimethylacetamide (C4H9NO), respectively. The crystal structure of I consists of [UO2(C5H4O4)(Dma)] layers, which have the crystal chemical formula AQ21M1 (A = (UO2)2+, Q21 = (C5H4O4)2−, M1 = Dma). The method of molecular Voronoi–Dirichlet polyhedra was employed to characterize intermolecular noncovalent interactions in the structure of I. A comparative analysis of noncovalent interactions in the structures of the title compound and the isomeric complex of uranyl citraconate with Dma was performed. An analysis of coordination modes of all itaconate-containing compounds from the CSD was performed.
Cite:
Uhanov A.S.
, Klepov V.V.
, Vologzhanina A.V.
, Zubavichus Y.
, Savchenkov A.
, Pushkin D.V.
, Serezhkina L.
, Serezhkin V.N.
New Itaconate-Containing Uranyl Complex Unit and Coordination Modes of Itaconate Ions
Comptes Rendus Chimie. 2020. V.23. N2. P.117-126. DOI: 10.5802/crchim.8 WOS Scopus РИНЦ
New Itaconate-Containing Uranyl Complex Unit and Coordination Modes of Itaconate Ions
Comptes Rendus Chimie. 2020. V.23. N2. P.117-126. DOI: 10.5802/crchim.8 WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Oct 2, 2019 |
Accepted: | Oct 28, 2019 |
Published online: | Jan 1, 2020 |
Published print: | Jun 19, 2020 |
Identifiers:
Web of science | WOS:000573968300002 |
Scopus | 2-s2.0-85100345186 |
Elibrary | 44960558 |
Chemical Abstracts | 2020:1764097 |
Chemical Abstracts (print) | 173:607691 |
OpenAlex | W3036574205 |