Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts
Review
| Общее |
Language:
Английский,
Genre:
Review,
Status:
Published,
Source type:
Original
|
| Journal |
Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences
ISSN: 1364-5021
, E-ISSN: 1471-2946
|
| Output data |
Year: 2012,
Volume: 468,
Number: 2143,
Pages: 2017-2034
Pages count
: 18
DOI:
10.1098/rspa.2012.0072
|
| Tags |
Allylic oxidation, Carboxylation, Cyclohexane, Metal-organic frameworks, MIL-101, Single-site heterogeneous catalysts |
| Authors |
Maksimchuk Nataliya V.
1
,
Zalomaeva Olga V.
1
,
Skobelev Igor Y.
1
,
Kovalenko Konstantin A.
2,3
,
Fedin Vladimir P.
1,3
,
Kholdeeva Oxana A.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
|
| 2 |
Nikolaev Institute of Inorganic Chemistry, pr. Lavrentieva 3, Novosibirsk 630090, Russia
|
| 3 |
Department of Inorganic Chemistry, Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia
|
|
Funding (2)
|
1
|
Russian Foundation for Basic Research
|
09-03-12112
|
|
2
|
Russian Foundation for Basic Research
|
09-03-93109
|
In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O2 and tert-butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO2. A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst’s resistance to metal leaching and the nature of catalysis.