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Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts Review

Общее Language: Английский, Genre: Review,
Status: Published, Source type: Original
Journal Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences
ISSN: 1364-5021 , E-ISSN: 1471-2946
Output data Year: 2012, Volume: 468, Number: 2143, Pages: 2017-2034 Pages count : 18 DOI: 10.1098/rspa.2012.0072
Tags Allylic oxidation, Carboxylation, Cyclohexane, Metal-organic frameworks, MIL-101, Single-site heterogeneous catalysts
Authors Maksimchuk Nataliya V. 1 , Zalomaeva Olga V. 1 , Skobelev Igor Y. 1 , Kovalenko Konstantin A. 2,3 , Fedin Vladimir P. 1,3 , Kholdeeva Oxana A. 1
Affiliations
1 Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
2 Nikolaev Institute of Inorganic Chemistry, pr. Lavrentieva 3, Novosibirsk 630090, Russia
3 Department of Inorganic Chemistry, Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia

Funding (2)

1 Russian Foundation for Basic Research 09-03-12112
2 Russian Foundation for Basic Research 09-03-93109

Abstract: In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O2 and tert-butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO2. A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst’s resistance to metal leaching and the nature of catalysis.
Cite: Maksimchuk N.V. , Zalomaeva O.V. , Skobelev I.Y. , Kovalenko K.A. , Fedin V.P. , Kholdeeva O.A.
Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts
Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences. 2012. V.468. N2143. P.2017-2034. DOI: 10.1098/rspa.2012.0072 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Files: Full text from publisher
Dates:
Submitted: Dec 30, 2011
Accepted: Feb 14, 2012
Published online: Mar 14, 2012
Published print: Jul 8, 2012
Identifiers:
publication_identifier.wos_identifier_type WOS:000304451200012
publication_identifier.scopus_identifier_type 2-s2.0-84862215157
publication_identifier.rinz_identifier_type 17991349
publication_identifier.accession_number_identifier_type 2012:1084342
publication_identifier.chemical_accession_number_identifier_type 157:307092
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