Flow Hydrogenation of 5-acetoxymethylfurfural over Cu-Based Catalysts
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Molecular Catalysis
ISSN: 2468-8231
|
| Output data |
Year: 2020,
Volume: 494,
Article number
: 111132,
Pages count
: 6
DOI:
10.1016/j.mcat.2020.111132
|
| Tags |
5-Acetoxymethylfurfural; Selective hydrogenation; Cu-based catalyst; Layered double hydroxide; Flow reactor |
| Authors |
Nuzhdin Alexey L.
1
,
Bukhtiyarova Marina V.
1
,
Bulavchenko Olga A.
1
,
Bukhtiyarova Galina A.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS, Ave. Lavrentiev 5, 630090, Novosibirsk Russia
|
|
Funding (2)
|
1
|
Federal Agency for Scientific Organizations
|
0303-2016-0004
|
|
2
|
Federal Agency for Scientific Organizations
|
0303-2016-0006 (V.44.1.6)
|
5-Acetoxymethylfurfural (AMF) is a promising starting material for synthesis of the valuable furan derivatives. The catalytic properties of Cu-based catalysts obtained from layered double hydroxides were studied in flow hydrogenation of AMF to 5-(acetoxymethyl)-2-furanmethanol (AMFM) in the present work. The resulting product can be easily converted to 2,5-bis(hydroxymethyl)furan which has significant potential in the production of polymers and pharmaceuticals. It was found that hydrogenation of AMF gives AMFM with selectivity of 98 % at the full conversion of the substrate under mild reaction conditions (90°C and 10 bar). The influence of the solvent nature, Cu/Al ratio and calcination temperature on the catalyst performance was investigated.