Diene Synthesis and One-Pot Processes in the Presence of Solutions of Mo–V–P Heteropoly Acids
Kinetics and Catalysis
, E-ISSN: 1608-3210
||anthraquinone; diene synthesis; heteropoly acids; naphthoquinone; oxidation
Federal Research Center Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
Federal Agency for Scientific Organizations
This review—which is based on the authors’ original studies—is devoted to application of aqueous solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of vanadium atoms) as bifunctional (acidic and oxidative) catalysts. The focus is on the development of one-pot processes in which the acid-catalyzed reaction of diene synthesis is combined with the oxidation of the produced adducts. Prospects for the design of a number of industrial processes for the production of substituted 1,4-naphtho- and 9,10-anthraquinones in the presence of solutions of modified non-Keggin HPA-x are shown. © 2020, Pleiades Publishing, Ltd.