Diene Synthesis and One-Pot Processes in the Presence of Solutions of Mo–V–P Heteropoly Acids
Review
| Общее |
Language:
Английский,
Genre:
Review,
Status:
Published,
Source type:
Translated
|
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Output data |
Year: 2020,
Volume: 61,
Number: 4,
Pages: 516-529
Pages count
: 14
DOI:
10.1134/S0023158420030118
|
| Tags |
anthraquinone; diene synthesis; heteropoly acids; naphthoquinone; oxidation |
| Authors |
Gogin L.G.
1
,
Zhizhina E.G.
1
|
| Affiliations |
| 1 |
Federal Research Center Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Funding (1)
|
1
|
Federal Agency for Scientific Organizations
|
0303-2016-0008
|
This review—which is based on the authors’ original studies—is devoted to application of aqueous solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of vanadium atoms) as bifunctional (acidic and oxidative) catalysts. The focus is on the development of one-pot processes in which the acid-catalyzed reaction of diene synthesis is combined with the oxidation of the produced adducts. Prospects for the design of a number of industrial processes for the production of substituted 1,4-naphtho- and 9,10-anthraquinones in the presence of solutions of modified non-Keggin HPA-x are shown. © 2020, Pleiades Publishing, Ltd.