Nanoconfinement Effects on Structural Anomalies in Imidazolium Ionic Liquids
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Nanoscale
ISSN: 2040-3364
, E-ISSN: 2040-3372
|
| Output data |
Year: 2020,
Volume: 12,
Number: 46,
Pages: 23480–23487
Pages count
: 8
DOI:
10.1039/d0nr06961b
|
| Authors |
Ivanov Mikhail Yu.
1,2
,
Poryvaev Artem S.
1,2
,
Polyukhov Daniil M.
1,3
,
Prikhod’ko Sergey A.
4
,
Adonin Nicolay Yu.
4
,
Fedin Matvey V.
1,2
|
| Affiliations |
| 1 |
International Tomography Center SB RAS
|
| 2 |
Novosibirsk State University
|
| 3 |
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS
|
| 4 |
Boreskov Institute of Catalysis SB RAS
|
|
Funding (2)
|
1
|
Russian Science Foundation
|
19-13-00071
|
|
2
|
Ministry of Science and Higher Education of the Russian Federation
|
14.W03.31.0034
|
Imidazolium Ionic Liquids (ILs) have been found to exhibit unusual nanostructuring behavior below their glass transition temperatures (Tg), which is ascribed to rearrangements in nonpolar domains formed by segregated alkyl chains. However, the dimensions required for such highly cooperative bulk phenomena are still unknown. In this work, we for the first time, investigate the effect of nanoconfinement on structural anomalies in imidazolium ILs. For this purpose, a series of ILs were embedded into the cavities of metal–organic framework (MOF) ZIF-8 and investigated using spin probes and Electron Paramagnetic Resonance (EPR) spectroscopy. The unusual nanostructuring near Tg, previously known for bulk ILs, was also observed for such nanoconfined ILs, and the amplitude of the anomaly was found to be dependent on the structure of the IL, thus showing the effects of molecular packing inside the MOF cavity. The first observation of structural anomalies in nanoconfined ILs opens perspectives for designing smart materials exhibiting these phenomena, and engaging MOFs as platforms creates the basis for potential applications of such functionalities.