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Supercritical Fluids in Chemistry Review

Общее Language: Английский, Genre: Review,
Status: Published, Source type: Translated
Journal Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837
Output data Year: 2020, Volume: 89, Number: 12, Pages: 1337-1427 Pages count : 91 DOI: 10.1070/rcr4932
Authors Alekseev Evgenii Sergeevich 1 , Alentiev Alexander Yur'evich 2 , Belova Anastasia Stanislavovna 3 , Bogdan Viktor Ignat'evich 4 , Tatiana Veniaminovna Tatiana Veniaminovna 4 , Bystrova Aleksandra Valerievna 5 , Gafarova Elvira Rasitovna 6 , Golubeva Elena Nikolaevna 1 , Grebenik Ekaterina Andreevna 6 , Gromov Oleg Igorevich 1 , Davankov Vadim Alexandrovich 3 , Zlotin Sergei Grigorievich 4 , Kiselev Mikhail Grigor'evich 7 , Koklin Aleksei Evgenievich 4 , Kononevich Yuriy Nikolaevich 3 , Lazhko Alexey Eduardovich 8 , Lunin Valerii Vasil'evich 1 , Lyubimov Sergey Evgen'evich 3 , Martyanov Oleg Nikolaevich 9 , Mishanin Igor Igorevich 4 , Muzafarov Aziz Mansurovich 3 , Nesterov Nikolay Sergeevich 9 , Nikolaev Alexander Yur'evich 3 , Roman Dmitrievich Roman Dmitrievich 7 , Parenago Olga Olegovna 8 , Parenago Oleg Pavlovich 2 , Pokusaeva Yana Andreevna 4 , Ronova Inga Alexandrovna 3 , Solovieva Anna Borisovna 10 , Temnikov Maxim Nikolaevich 3 , Timashev Peter Sergeevich 10 , Turova Olga Vasil'evna 4 , Filatova Evgeniya Viktorovna 4 , Philippov Alexey Aleksandrovich 9 , Chibiryaev Andrey Mikhailovich 9 , Shalygin Anton Sergeevich 9
Affiliations
1 Московский государственный университет имени М.В.Ломоносова
2 Институт нефтехимического синтеза имени А.В.Топчиева
3 Институт элементоорганических соединений имени А.Н.Несмеянова
4 Институт органической химии имени Н.Д.Зелинского
5 Институт синтетических полимерных материалов имени Н.С.Ениколопова
6 Первый Московский государственный медицинский университет имени И.М.Сеченова (Сеченовский университет)
7 Институт химии растворов имени Г.А.Крестова
8 Институт общей и неорганической химии имени Н.С.Курнакова
9 Институт катализа им. Г.К.Борескова Сибирского отделения Российской академии наук
10 Институт химической физики имени Н.Н.Семенова

Funding (18)

1 Russian Foundation for Basic Research 18-29-06022
2 Ministry of Science and Higher Education of the Russian Federation 075-15-2019-1876
3 Russian Foundation for Basic Research 18-29-06032 (АААА-А18-118071990084-2)
4 Russian Foundation for Basic Research 18-29-06072 (АААА-А18-118072590020-1)
5 Russian Science Foundation 18-73-10153 (АААА-А18-118110990067-1)
6 Ministry of Science and Higher Education of the Russian Federation 14.W03.31.0018 (АААА-А19-119011890058-9)
7 Russian Foundation for Basic Research 18-03-00275 (АААА-А18-118020990090-1)
8 Russian Foundation for Basic Research 18-29-09166 (АААА-А19-119051690097-6)
9 Russian Science Foundation 20-73-10180
10 Russian Science Foundation 19-19-00614
11 Ministry of Science and Higher Education of the Russian Federation 0082-2019-0012 (АААА-А20-120021190043-7)
12 Russian Foundation for Basic Research 18-29-06019 (АААА-А18-118122590067-8)
13 Russian Foundation for Basic Research 18-29-06059 (АААА-А18-118071990048-4)
14 Russian Foundation for Basic Research 18-33-00982 (АААА-А18-118032990088-1)
15 Russian Foundation for Basic Research 18-29-06008
16 Russian Science Foundation 18-15-00401 (АААА-А18-118062790040-8)
17 Russian Foundation for Basic Research 18-03-00255 (АААА-А18-118012290098-9)
18 Russian Foundation for Basic Research 19-13-50154 (АААА-А20-120081390043-9)

Abstract: This review analyzes the rapidly developing applications of supercritical fluids, mainly supercritical carbon dioxide, in catalysis, chemistry of high-molecular-weight compounds, and medicinal chemistry in Russia and abroad. It considers the methods of catalyst preparation based on impregnation of inorganic and organic supports with metal-containing compounds, immobilization of organometallic and metal complex reagents in matrices of oxide and polymer supports, and deposition processes employing supercritical fluids. An analysis is presented of the prospects for applying CO2 and some organic compounds, such as aliphatic alcohols, in sub- and supercritical states as reactants and (or) solvents for catalytic reactions of hydrocarbon isomerization and cracking, hydrogenation, dehydrogenation, oxidation, etc, including the asymmetric reactions. The review discusses processes of synthesizing and modifying polymer materials for various purposes, including aerogels, foams, and composites impregnated with photochromes, in a supercritical fluid medium. Special attention is paid to supercritical one-pot, which make the techniques of obtaining new materials simpler, less expensive, and more efficient. The work investigates the effect of supercritical CO2 on the morphology, gas separation characteristics, and dielectric properties of polymers. One of the promising applications of supercritical fluids in medicine that is discussed in this study is their use in transplantology and pharmacology, for example, for obtaining drug polymorphs with higher bioavailability. The review also provides an overview of the recent data on the use of EPR spectroscopy for studying the properties of supercritical fluids, including those exhibited in the vicinity of the critical point and identifying the intermediates of chemical reactions in such media. The bibliography includes 1151 references.
Cite: Alekseev E.S. , Alentiev A.Y. , Belova A.S. , Bogdan V.I. , Tatiana Veniaminovna T.V. , Bystrova A.V. , Gafarova E.R. , Golubeva E.N. , Grebenik E.A. , Gromov O.I. , Davankov V.A. , Zlotin S.G. , Kiselev M.G. , Koklin A.E. , Kononevich Y.N. , Lazhko A.E. , Lunin V.V. , Lyubimov S.E. , Martyanov O.N. , Mishanin I.I. , Muzafarov A.M. , Nesterov N.S. , Nikolaev A.Y. , Roman Dmitrievich R.D. , Parenago O.O. , Parenago O.P. , Pokusaeva Y.A. , Ronova I.A. , Solovieva A.B. , Temnikov M.N. , Timashev P.S. , Turova O.V. , Filatova E.V. , Philippov A.A. , Chibiryaev A.M. , Shalygin A.S.
Supercritical Fluids in Chemistry
Russian Chemical Reviews. 2020. V.89. N12. P.1337-1427. DOI: 10.1070/rcr4932 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Алексеев Е.С. , Алентьев А.Ю. , Белова А.С. , Богдан В.И. , Богдан Т.В. , Быстрова А.В. , Гафарова Э.Р. , Голубева Е.Н. , Гребеник Е.А. , Громов О.И. , Даванков В.А. , Злотин С.Г. , Киселев М.Г. , Коклин А.Е. , Кононевич Ю.Н. , Лажко А.Э. , Лунин В.В. , Любимов С.Е. , Мартьянов О.Н. , Мишанин И.И. , Музафаров А.М. , Нестеров Н.С. , Николаев А.Ю. , Опарин Р.Д. , Паренаго О.О. , Паренаго О.П. , Покусаева Я.А. , Ронова И.А. , Соловьева А.Б. , Темников Б.Н. , Тимашев П.С. , Турова О.В. , Филатова Е.В. , Филиппов А.А. , Чибиряев А.М. , Шалыгин А.С.
Сверхкритические флюиды в химии
Успехи химии. 2020. Т.89. №12. С.1337-1427. DOI: 10.1070/RCR4932?locatt=label:RUSSIA publication_identifier_short.rinz_identifier_type
Dates:
Published print: Dec 1, 2020
Published online: Dec 31, 2020
Identifiers:
publication_identifier.wos_identifier_type WOS:000604750000001
publication_identifier.scopus_identifier_type 2-s2.0-85097877755
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