An Unusually Stable Pyridine-2-selenenyl Chloride: Structure and Reactivity Full article
Journal |
Structural Chemistry
ISSN: 1040-0400 , E-ISSN: 1572-9001 |
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Output data | Year: 2016, Volume: 27, Number: 6, Pages: 1733-1741 Pages count : 9 DOI: 10.1007/s11224-016-0845-3 | ||||||||||||
Tags | Pyridine-2-selenenyl chloride; T-shaped adduct; Conformational analysis; Molecular structure; DFT calculation; Crystal structure | ||||||||||||
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Abstract:
According to an X-ray diffraction study, pyridine-2-selenenyl chloride (1) characterized by unusually high stability both in solutions and in the solid state adopts a dimeric structure formed by two secondary intermolecular Se···N interactions. However, it slowly transforms into zwitterionic T-shaped pyridinium-2-selenenyl dichloride (2) in a dichloromethane solution. Conformational features, electronic structures, and reactivities of 1 and 2 are discussed on the basis of experimental and theoretical (quantum chemical calculations) data.
Cite:
Khrustalev V.N.
, Matsulevich Z.V.
, Aysin R.R.
, Lukiyanova J.M.
, Fukin G.K.
, Zubavichus Y.V.
, Askerov R.K.
, Maharramov A.M.
, Borisov A.V.
An Unusually Stable Pyridine-2-selenenyl Chloride: Structure and Reactivity
Structural Chemistry. 2016. V.27. N6. P.1733-1741. DOI: 10.1007/s11224-016-0845-3 WOS Scopus РИНЦ
An Unusually Stable Pyridine-2-selenenyl Chloride: Structure and Reactivity
Structural Chemistry. 2016. V.27. N6. P.1733-1741. DOI: 10.1007/s11224-016-0845-3 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 15, 2016 |
Accepted: | Aug 31, 2016 |
Published online: | Sep 10, 2016 |
Published print: | Dec 1, 2016 |
Identifiers:
Web of science | WOS:000386373500017 |
Scopus | 2-s2.0-84986253619 |
Elibrary | 27572974 |
Chemical Abstracts | 2016:1491283 |
Chemical Abstracts (print) | 165:452003 |
OpenAlex | W2512788537 |