Pd–Cu Catalyst Prepared from Heterobimetallic PdCu2(OAc)6: an XRD-EXAFS Study and Activity/Selectivity in the Liquid-Phase Hydrogenation of a C≡C Bond Full article
Journal |
Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X |
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Output data | Year: 2016, Volume: 26, Number: 6, Pages: 502-504 Pages count : 3 DOI: 10.1016/j.mencom.2016.11.014 | ||||
Tags | SELECTIVE HYDROGENATION; SURFACE SEGREGATION; IN NANOPARTICLES; ACETYLENE; COMPLEXES | ||||
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Abstract:
The formation of a PdCu alloy with an fcc structure in 1% Pd–1.2% Cu2 /Al2O3 (as evidenced by XRD and EXAFS data) significantly improves catalyst selectivity in the semihydrogenation of internal and terminal alkynes, which makes 1% Pd–1.2% Cu2 /Al2O3 a promising alternative to the commercial Lindlar catalyst.
Cite:
Markov P.V.
, Bragina G.O.
, Rassolov A.V.
, Baeva G.N.
, Mashkovsky I.S.
, Murzin V.Y.
, Zubavichus Y.V.
, Stakheev A.Y.
Pd–Cu Catalyst Prepared from Heterobimetallic PdCu2(OAc)6: an XRD-EXAFS Study and Activity/Selectivity in the Liquid-Phase Hydrogenation of a C≡C Bond
Mendeleev Communications. 2016. V.26. N6. P.502-504. DOI: 10.1016/j.mencom.2016.11.014 WOS Scopus РИНЦ
Pd–Cu Catalyst Prepared from Heterobimetallic PdCu2(OAc)6: an XRD-EXAFS Study and Activity/Selectivity in the Liquid-Phase Hydrogenation of a C≡C Bond
Mendeleev Communications. 2016. V.26. N6. P.502-504. DOI: 10.1016/j.mencom.2016.11.014 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 28, 2016 |
Published print: | Nov 1, 2016 |
Published online: | Nov 24, 2016 |
Identifiers:
Web of science | WOS:000390515200014 |
Scopus | 2-s2.0-84997501275 |
Elibrary | 27579042 |
Chemical Abstracts | 2016:1959555 |
Chemical Abstracts (print) | 166:65068 |
OpenAlex | W2556342852 |