Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2017, Volume: 66, Number: 9, Pages: 1563-1568 Pages count : 6 DOI: 10.1007/s11172-017-1925-2

Tags

copper(i); ferrocenylpyrazole; Group 11 metal pyrazolates; silver(i)

Authors

Titov A.A. ^1,2 , Smol´yakov A.F. ^1,2 , Rodionov A.N. ¹ , Kosenko I.D. ¹ , Guseva E.A. ¹ , Zubavichus Ya.V. ³ , Dorovatovskii P.V. ³ , Filippov O.A. ¹ , Shubina E.S. ¹

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2	Peoples´ Friendship University of Russia
3	National Research Center "Kurchatov Institute"

New tri- and tetranuclear macrocyclic silver(I) and copper(I) 3-ferrocenyl-5-(trifluoromethyl)pyrazolates were prepared: [{(3-((η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}M]3 (M = Cu (1), Ag (2)) and [{(3-(( η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}Cu]4 (3). The structures of compounds were established by X-ray diffraction analysis. In the crystalline state, a planar trinuclear silver-containing macrocycliс pyrazolate and a saddle-shaped tetranuclear copper-containing macrocycle are formed. The introduction of a bulky substituent, ferrocene, into the pyrazole ligand results in complete shielding of the acidic metal sites, which precludes the coordination of base molecules.

Titov A.A. , Smol´yakov A.F. , Rodionov A.N. , Kosenko I.D. , Guseva E.A. , Zubavichus Y.V. , Dorovatovskii P.V. , Filippov O.A. , Shubina E.S.
Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates
Russian Chemical Bulletin. 2017. V.66. N9. P.1563-1568. DOI: 10.1007/s11172-017-1925-2 WOS Scopus РИНЦ

Титов А.А. , Смольяков А.Ф. , Родионов А.Н. , Косенко И.Д. , Гусева Е.А. , Зубавичус Я.В. , Дороватовский П.В. , Филиппов О.А. , Шубина Е.С.
Ферроценсодержащие трех- и четырехъядерные циклические пиразолаты меди(I) и серебра(I)
Известия Академии наук. Серия химическая. 2017. №9. С.1563-1568. РИНЦ

Submitted:	Jun 26, 2017
Accepted:	Jul 3, 2017
Published print:	Sep 1, 2017
Published online:	Dec 28, 2017

Web of science	WOS:000418825200006
Scopus	2-s2.0-85039435719
Elibrary	35512734
Chemical Abstracts	2018:16611
Chemical Abstracts (print)	168:144405
OpenAlex	W2776060911