Optical Readout of Controlled Monomer–Dimer Self-Assembly Full article
Journal |
Dalton Transactions
ISSN: 1477-9226 , E-ISSN: 1477-9234 |
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Output data | Year: 2018, Volume: 47, Number: 40, Pages: 14169-14173 Pages count : 5 DOI: 10.1039/c8dt00384j | ||||||||||||||||
Tags | ANNULATED DIAZEPINE RINGS; SPECTRAL PROPERTIES; MG-II; PORPHYRAZINES; COMPLEXES; SUBSTITUENTS | ||||||||||||||||
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Abstract:
5,7-Substituted 1,4-diazepinoporphyrazine magnesium(II) complexes were synthesized via Mg(II)-alkoxide templated macrocyclization. A single crystal growth synchrotron diffraction analysis permitted what is to our knowledge the first structural characterization of a 1,4-diazepinoporphyrazine. It exists as a dimer in the solid state. In silico calculations supported by solution phase spectral studies involving a series of representative derivatives, provided insights into the factors governing dimerization of 1,4-diazepinoporphyrazines. The present 1,4-diazepinoporphyrazines serve as useful probes for understanding the determinants that guide dimer–monomer equilibria and the self-assembly of phthalocyanine derivatives.
Cite:
Tarakanov P.A.
, Tarakanova E.N.
, Dorovatovskii P.V.
, Zubavichus Y.V.
, Khrustalev V.N.
, Trashin S.A.
, De Wael K.
, Neganova M.E.
, Mischenko D.V.
, Sessler J.L.
, Stuzhin P.A.
, Pushkarev V.E.
, Tomilova L.G.
Optical Readout of Controlled Monomer–Dimer Self-Assembly
Dalton Transactions. 2018. V.47. N40. P.14169-14173. DOI: 10.1039/c8dt00384j WOS Scopus РИНЦ
Optical Readout of Controlled Monomer–Dimer Self-Assembly
Dalton Transactions. 2018. V.47. N40. P.14169-14173. DOI: 10.1039/c8dt00384j WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Jan 29, 2018 |
Accepted: | Apr 4, 2018 |
Published online: | Apr 10, 2018 |
Published print: | Oct 28, 2018 |
Identifiers:
Web of science | WOS:000447708900005 |
Scopus | 2-s2.0-85054891596 |
Elibrary | 38642727 |
Chemical Abstracts | 2018:723460 |
Chemical Abstracts (print) | 169:416705 |
OpenAlex | W2797593241 |