New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation Full article
Journal |
Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Output data | Year: 2018, Volume: 88, Number: 7, Pages: 1441-1450 Pages count : 10 DOI: 10.1134/s1070363218070150 | ||||||||||
Tags | Schiff base, metal complexes, 4-methyl-7-hydroxy-8-formylcoumarin, N-aminomercaptotriazole | ||||||||||
Authors |
|
||||||||||
Affiliations |
|
Abstract:
A new Schiff base was prepared by the reaction of 4-methyl-7-hydroxy-8-formylcoumarin with N-aminomercaptotriazole. In solution and in solid phase the compound was shown to exist in the thione form. The compound reacts with Cu(II), Ni(II), Zn(II) and Cd(II) ions depending on the metal salt to give complexes of composition ML2 or MHLX, where HL is monodeprotonated form of the ligand. Cu(II) and Ni(II) complexes were studied by spectral and magnetochemical methods. The Zn(II) and Cd(II) complexes exhibit fluorescence.
Cite:
Popov L.D.
, Borodkin S.A.
, Vasil’chenko I.S.
, Vlasenko V.G.
, Borodkin G.S.
, Zubavichus Y.V.
, Levchenkov S.I.
, Tupolova Y.P.
, Revinskii Y.V.
, Shcherbakov I.N.
New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation
Russian Journal of General Chemistry. 2018. V.88. N7. P.1441-1450. DOI: 10.1134/s1070363218070150 WOS Scopus РИНЦ
New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation
Russian Journal of General Chemistry. 2018. V.88. N7. P.1441-1450. DOI: 10.1134/s1070363218070150 WOS Scopus РИНЦ
Original:
Попов Л.Д.
, Бородкин С.А.
, Васильченко И.С.
, Власенко В.Г.
, Бородкин Г.С.
, Зубавичус Я.В.
, Левченков С.И.
, Туполова Ю.П.
, Ревинский Ю.В.
, Щербаков И.Н.
Новое тридентатное основание шиффа – продукт конденсации 4-метил-7-гидрокси-8-формилкумарина и n-аминомеркаптотриазола: синтез, строение и комплексообразование
Журнал общей химии. 2018. Т.88. №7. С.1149–1158. DOI: 10.1134/S0044460X18070156 РИНЦ
Новое тридентатное основание шиффа – продукт конденсации 4-метил-7-гидрокси-8-формилкумарина и n-аминомеркаптотриазола: синтез, строение и комплексообразование
Журнал общей химии. 2018. Т.88. №7. С.1149–1158. DOI: 10.1134/S0044460X18070156 РИНЦ
Dates:
Submitted: | Feb 22, 2018 |
Published print: | Jul 1, 2018 |
Published online: | Sep 4, 2018 |
Identifiers:
Web of science | WOS:000443716500015 |
Scopus | 2-s2.0-85052801021 |
Elibrary | 35755442 |
Chemical Abstracts | 2018:1663559 |
Chemical Abstracts (print) | 169:384881 |
OpenAlex | W2890102746 |