Tridecanuclear CuII11Na2 Cagelike Silsesquioxanes Full article
Journal |
Crystal Growth and Design
ISSN: 1528-7483 , E-ISSN: 1528-7505 |
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Output data | Year: 2018, Volume: 18, Number: 9, Pages: 5377-5384 Pages count : 8 DOI: 10.1021/acs.cgd.8b00778 | ||||||||
Tags | Coordination reactions; Metal ions; Self assembly | ||||||||
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Abstract:
A series of three unprecedented heterometallic copper(II) sodium silsesquioxanes were isolated (i) via the unusual rearrangement process during synthesis of coordination polymers or (ii) via the self-assembly reaction using 2,2′-bipyridine. The unique type of these products’ molecular topology consists of an unusual fusion of two sandwich-like components (each including five copper and one sodium sites) via a central copper ion. These compounds correspond to the highest nuclearity among Cu(II)-based cage silsesquioxanes reported to date.
Cite:
Astakhov G.S.
, Bilyachenko A.N.
, Levitsky M.M.
, Korlyukov A.A.
, Zubavichus Y.V.
, Dorovatovskii P.V.
, Khrustalev V.N.
, Vologzhanina A.V.
, Shubina E.S.
Tridecanuclear CuII11Na2 Cagelike Silsesquioxanes
Crystal Growth and Design. 2018. V.18. N9. P.5377-5384. DOI: 10.1021/acs.cgd.8b00778 WOS Scopus РИНЦ
Tridecanuclear CuII11Na2 Cagelike Silsesquioxanes
Crystal Growth and Design. 2018. V.18. N9. P.5377-5384. DOI: 10.1021/acs.cgd.8b00778 WOS Scopus РИНЦ
Dates:
Submitted: | May 21, 2018 |
Accepted: | Jul 5, 2018 |
Published online: | Jul 9, 2018 |
Published print: | Sep 5, 2018 |
Identifiers:
Web of science | WOS:000444218400068 |
Scopus | 2-s2.0-85049881947 |
Elibrary | 35768178 |
Chemical Abstracts | 2018:1279935 |
OpenAlex | W2821178211 |