Study of the Nature of the Chemical Bond in the Outer-Sphere Adducts of Electrically Neutral Complexes and Organic Molecules Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
||
---|---|---|---|
Output data | Year: 1979, Volume: 19, Number: 5, Pages: 686–693 Pages count : 8 DOI: 10.1007/BF00752830 | ||
Tags | Physical Chemistry; Inorganic Chemistry ; Adduct; Chemical Bond; Organic Molecule | ||
Authors |
|
||
Affiliations |
|
Abstract:
Outer-sphere complex formation by various organic molecules with the B-diketonato compounds of transition metals have been studied by NMR. The effective stability constants of the complexes and the effective spin-lattice relaxation times of the protons of the ligands have been measured. It has been concluded that there are two types of coordination of the outer-sphere ligands: that due to hydrogen bonding with the oxygen atoms of the chelate compounds, and that due to interaction with the T-system of these chelate compounds.
Cite:
Kitaigorodskii A.N.
, Nekipelov V.M.
, Zamaraev K.I.
Study of the Nature of the Chemical Bond in the Outer-Sphere Adducts of Electrically Neutral Complexes and Organic Molecules
Journal of Structural Chemistry. 1979. V.19. N5. P.686–693. DOI: 10.1007/BF00752830 Scopus РИНЦ
Study of the Nature of the Chemical Bond in the Outer-Sphere Adducts of Electrically Neutral Complexes and Organic Molecules
Journal of Structural Chemistry. 1979. V.19. N5. P.686–693. DOI: 10.1007/BF00752830 Scopus РИНЦ
Original:
Китайгородский А.Н.
, Некипелов В.М.
, Замараев К.И.
Изучение природы химической связи во внешнесферных аддуктах электронейтральных комплексов и органических молекул
Журнал структурной химии. 1978. Т.19. №5. С.796-803. РИНЦ
Изучение природы химической связи во внешнесферных аддуктах электронейтральных комплексов и органических молекул
Журнал структурной химии. 1978. Т.19. №5. С.796-803. РИНЦ
Dates:
Submitted: | Apr 20, 1977 |
Published print: | Sep 1, 1979 |
Identifiers:
Scopus | 2-s2.0-34250280433 |
Elibrary | 46662259 |
OpenAlex | W2024248982 |
Citing:
DB | Citing |
---|---|
Scopus | 2 |