Giant Palladium Clusters: Synthesis and Characterization Full article
Conference |
1992 MRS Spring Meeting 27 Apr - 1 May 1992 , San Francisco, California |
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Source | Chemical Processes in Inorganic Materials:: Volume 272: Metal and Semiconductor Clusters and Colloids (MRS Proceedings) Illustrated Edition Compilation, Cambridge University Press; Illustrated edition (October 12, 1992). 1992. 350 c. ISBN 1558991670. |
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Journal |
MRS Online Proceedings Library
ISSN: 1946-4274 |
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Output data | Year: 1992, Volume: 272, Number: 1, Pages: 139-150 Pages count : 12 DOI: 10.1557/proc-272-139 | ||||
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Abstract:
A series of palladium clusters containing from 4 to some hundred Pd atoms in the metal skeleton was prepared and characterized with structural data as well as by chemical properties including catalytic activity. An agreement between X-ray and EXAFS data was obtained for single-crystal low-molecular clusters. Giant clusters approximated as Pd56L60(OCOCH3)180 (L=Phen, Bipy) and Pd561Phen60O60X60 (X = PF6, CIO4, SO4, BF4, CF3COO)were characterized with TEM, SAXS, EXAFS, NMR, and magnetic susceptibility data. The clusters consisting of close-packed metal core and L, X ligands at its periphery could be considered as a bridge between low-molecular clusters and the particles of colloidal metals.
Cite:
Moiseev I.I.
, Vargaftik M.N.
, Zamaraev K.I.
, Kochubey D.I.
Giant Palladium Clusters: Synthesis and Characterization
In compilation Chemical Processes in Inorganic Materials:: Volume 272: Metal and Semiconductor Clusters and Colloids (MRS Proceedings) Illustrated Edition. – Cambridge University Press; Illustrated edition (October 12, 1992)., 1992. – C.139-150. – ISBN 1558991670. DOI: 10.1557/proc-272-139 WOS РИНЦ
Giant Palladium Clusters: Synthesis and Characterization
In compilation Chemical Processes in Inorganic Materials:: Volume 272: Metal and Semiconductor Clusters and Colloids (MRS Proceedings) Illustrated Edition. – Cambridge University Press; Illustrated edition (October 12, 1992)., 1992. – C.139-150. – ISBN 1558991670. DOI: 10.1557/proc-272-139 WOS РИНЦ
Dates:
Published online: | May 15, 1992 |
Published print: | Dec 1, 1992 |
Identifiers:
Web of science | WOS:A1992BW93S00019 |
Elibrary | 46446306 |
OpenAlex | W2326211828 |