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Tetrapalladium-Containing Polyoxotungstate [PdII4(α-P2W15O56)2]16−: A Comparative Study Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X
Output data Year: 2014, Volume: 53, Number: 21, Pages: 11778 - 11784 Pages count : 7 DOI: 10.1021/ic502080x
Authors Izarova Natalya V. 1,2 , Maksimovskaya Raisa I. 4 , Willbold Sabine 3 , Kogerler Paul 1,5
Affiliations
1 Peter Grünberg Institute - PGI 6
2 Nikolaev Institute of Inorganic Chemistry, 630090 Novosibirsk, Russia
3 Central Institute for Engineering, Electronics and Analytics - ZEA-3, Forschungszentrum Jülich, D-52425 Jülich, Germany
4 Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
5 Institute of Inorganic Chemistry, RWTH Aachen University, D-52074 Aachen, Germany

Funding (1)

1 European Commission 308051 FP7-IDEAS-ERC MOLSPINTRON

Abstract: The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16− has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV−vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions.
Cite: Izarova N.V. , Maksimovskaya R.I. , Willbold S. , Kogerler P.
Tetrapalladium-Containing Polyoxotungstate [PdII4(α-P2W15O56)2]16−: A Comparative Study
Inorganic Chemistry. 2014. V.53. N21. P.11778 - 11784. DOI: 10.1021/ic502080x publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Aug 28, 2014
Published online: Oct 17, 2014
Published print: Nov 3, 2014
Identifiers:
publication_identifier.wos_identifier_type WOS:000344307400048
publication_identifier.scopus_identifier_type 2-s2.0-84908626185
publication_identifier.rinz_identifier_type 23998005
publication_identifier.accession_number_identifier_type 2014:1767960
publication_identifier.chemical_accession_number_identifier_type 161:654232
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