Manifestation of the Adsorbed CO Diffusion Anisotropy Caused by the Structure Properties of the Pd(110) – (1×2) Surface on the Oscillatory Behaviour during CO Oxidation Reaction – Monte-Carlo Model Full article
Conference |
Catalysis for sustainable development : Russian-Dutch Workshop 22-26 Jun 2002 , Novosibirsk, Russia |
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Journal |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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Output data | Year: 2003, Volume: 11, Number: 1, Pages: 173-180 Pages count : 8 | ||
Authors |
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Affiliations |
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Funding (3)
1 | Russian Foundation for Basic Research | 02-03-32568 |
2 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 99-01882 |
3 | Zamaraev International Charitable Scientific Foundation |
Abstract:
The modelling of self-oscillations and surface autowaves in CO oxidation reaction over Pd(110) has been carried out by means of the Monte-Carlo technique. The synchronous oscillations of the reaction rate and surface coverages are exhibited within the range of the suggested model parameters (under the conditions very close to the experimental observations). The dependencies of the simulation results on the lattice size and on the diffusion intensity have been studied. It has been established that the adsorbed CO diffusion anisotropy does not influence the oscillation kinetics but leads to the appearance of the propagating reaction fronts on the palladium surface elliptically stretched along the [110] direction in close agreement with the known experimental data.
Cite:
Matveev A.V.
, Latkin E.I.
, Elokhin V.I.
, Gorodetskii V.V.
Manifestation of the Adsorbed CO Diffusion Anisotropy Caused by the Structure Properties of the Pd(110) – (1×2) Surface on the Oscillatory Behaviour during CO Oxidation Reaction – Monte-Carlo Model
Chemistry for Sustainable Development. 2003. V.11. N1. P.173-180. РИНЦ
Manifestation of the Adsorbed CO Diffusion Anisotropy Caused by the Structure Properties of the Pd(110) – (1×2) Surface on the Oscillatory Behaviour during CO Oxidation Reaction – Monte-Carlo Model
Chemistry for Sustainable Development. 2003. V.11. N1. P.173-180. РИНЦ
Original:
Matveev A.V.
, Latkin E.I.
, Elokhin V.I.
, Gorodetskii V.V.
Manifestation of the Adsorbed CO Diffusion Anisotropy Caused by the Structure Properties of the Pd(110) - (1×2) Surface on the Oscillatory Behavior during CO Oxidation Reaction - Monte-Carlo Model
Химия в интересах устойчивого развития. 2003. V.11. N1. P.173-180. РИНЦ
Manifestation of the Adsorbed CO Diffusion Anisotropy Caused by the Structure Properties of the Pd(110) - (1×2) Surface on the Oscillatory Behavior during CO Oxidation Reaction - Monte-Carlo Model
Химия в интересах устойчивого развития. 2003. V.11. N1. P.173-180. РИНЦ
Identifiers:
Elibrary | 30644041 |
Citing:
DB | Citing |
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Elibrary | 1 |