Development of New Methods in Modern Selective Organic Synthesis: Preparation of Functionalized Molecules with Atomic Precision | Sciact - CRIS-system of Boreskov Institute of Catalysis

1	N D Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	St Petersburg State University, Universitetskaya nab. 7 ± 9, 199034 St Petersburg, Russian Federation
3	G K Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Akademika Lavrentieva 5, 630090 Novosibirsk, Russian Federation
4	Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russian Federation
5	Department of Chemistry, M V Lomonosov Moscow State University, Leninskie Gory 1, build. 3, 119991 Moscow, Russian Federation
6	International Tomography Center, Siberian Branch of the Russian Academy of Sciences, ul. Institutskaya 3a, 630090 Novosibirsk, Russian Federation
7	Institute of Hydrocarbon Processing, Siberian Branch of the Russian Academy of Sciences, ul. Neftezavodskaya 54, 644040 Omsk, Russian Federation
8	A N Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991 Moscow, Russian Federation
9	A V Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, 119991 Moscow, Russian Federation
10	N S Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, 117393 Moscow, Russian Federation
11	Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, ul. Pervomaiskaya 91, 620990 Ekaterinburg, Russian Federation
12	Ural Federal University named after the First President of Russia B N Yeltsin, ul. Mira 19, 620002 Ekaterinburg, Russian Federation
13	Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, ul. Socialisticheskaya 1, 659322 Biysk, Altai Krai, Russian Federation

Funding (30)

1	Russian Foundation for Basic Research	14-03-93183
2	Russian Foundation for Basic Research	14-03-00374
3	Президиум РАН	24.51
4	Russian Foundation for Basic Research	12-03-00403
5	Council for Grants of the President of the Russian Federation	МК-4391.2013.3
6	Russian Foundation for Basic Research	14-03-31239 (01201450183)
7	Council for Grants of the President of the Russian Federation	НШ-5340.2014.3
8	Russian Foundation for Basic Research	12-03-00557
9	Russian Foundation for Basic Research	12-03-31487
10	Russian Foundation for Basic Research	12-03-93111
11	Russian Foundation for Basic Research	13-03-01003
12	Russian Foundation for Basic Research	13-03-01210
13	Russian Foundation for Basic Research	13-03-01315
14	Russian Foundation for Basic Research	13-03-12074
15	Russian Foundation for Basic Research	13-03-12176 (01201367716)
16	Russian Foundation for Basic Research	13-03-12178
17	Russian Foundation for Basic Research	13-03-12193 (01201368704)
18	Russian Foundation for Basic Research	13-03-12231
19	Russian Foundation for Basic Research	13-03-12240
20	Russian Foundation for Basic Research	13-03-12258 (01201369479)
21	Russian Foundation for Basic Research	13-03-12451
22	Russian Foundation for Basic Research	13-03-90413
23	Russian Foundation for Basic Research	14-03-00237
24	Russian Foundation for Basic Research	14-03-00293
25	Russian Foundation for Basic Research	14-03-00869 (01201456868)
26	Russian Foundation for Basic Research	14-03-31119
27	Russian Foundation for Basic Research	14-03-31465
28	Skolkovo Foundation
29	Council for Grants of the President of the Russian Federation	МД-4750.2013.3
30	Council for Grants of the President of the Russian Federation	МК-1329.2014.3

The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend — the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as 'atomic precision' in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.

Ananikov V.P. , Khemchyan L.L. , Ivanova Y.V. , Bukhtiyarov V.I. , Sorokin A.M. , Prosvirin I.P. , Vatsadze S.Z. , Medvedʹko A.V. , Nuriev V.N. , Dilman A.D. , Levin V.V. , Koptyug I.V. , Kovtunov K.V. , Zhivonitko V.V. , Likholobov V.A. , Romanenko A.V. , Simonov P.A. , Nenajdenko V.G. , Shmatova O.I. , Muzalevskiy V.M. , Nechaev M.S. , Asachenko A.F. , Morozov O.S. , Dzhevakov P.B. , Osipov S.N. , Vorobyeva D.V. , Topchiy M.A. , Zotova M.A. , Ponomarenko S.A. , Borshchev O.V. , Luponosov Y.N. , Rempel A.A. , Valeeva A.A. , Stakheev A.Y. , Turova O.V. , Mashkovsky I.S. , Sysolyatin S.V. , Malykhin V.V. , Bukhtiyarova G.A. , Terentʹev A.O. , Krylov I.B.
Development of New Methods in Modern Selective Organic Synthesis: Preparation of Functionalized Molecules with Atomic Precision
Russian Chemical Reviews. 2014. V.83. N10. P.885-985. DOI: 10.1070/RC2014v83n10ABEH004471 PublicationIdentifierType_short.WOS PublicationIdentifierType_short.SCOPUS PublicationIdentifierType_short.RINZ PublicationIdentifierType_short.AN: 2014:2092188 PublicationIdentifierType_short.CAN: 162:189755

Анаников В.П. , Хемчян Л.Л. , Иванова Ю.В. , Бухтияров В.И. , Сорокин А.М. , Просвирин И.П. , Вацадзе С.З. , Медведько А.В. , Нуриев В.Н. , Дильман А.Д. , Левин В.В. , Коптюг И.В. , Ковтунов К.В. , Живонитко В.В. , Лихолобов В.А. , Романенко А.В. , Симонов П.А. , Ненайденко В.Г. , Шматова О.И. , Музалевский В.М. , Нечаев М.С. , Асаченко А.Ф. , Морозов О.С. , Джеваков П.Б. , Осипов С.Н. , Воробьева Д.В. , Топчий М.А. , Зотова М.А. , Пономаренко С.А. , Борщев О.В. , Лупоносов Ю.Н. , Ремпель А.А. , Валеева А.А. , Стахеев А.Ю. , Турова О.В. , Машковский И.С. , Сысолятин С.В. , Малыхин В.В. , Бухтиярова Г.А. , Терентьев А.О. , Крылов И.Б.
Развитие методологии современного селективного органического синтеза: получение функционализированных молекул с атомарной точностью
Успехи химии. 2014. Т.83. №10. С.885-985. DOI: 10.1070/RC2014v083n10ABEH004471?locatt=label:RUSSIAN PublicationIdentifierType_short.RINZ

Submitted:	May 30, 2014
Published print:	Oct 31, 2014
Published online:	Nov 9, 2014

Chemical Abstracts	2014:2092188
Chemical Abstracts (print)	162:189755
Web of science	WOS:000344941600002
Scopus	2-s2.0-84907452759
Rinz	23990954