Abstract: The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend — the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as 'atomic precision' in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.

Cite: Ananikov V.P. , Khemchyan L.L. , Ivanova Y.V. , Bukhtiyarov V.I. , Sorokin A.M. , Prosvirin I.P. , Vatsadze S.Z. , Medvedʹko A.V. , Nuriev V.N. , Dilman A.D. , Levin V.V. , Koptyug I.V. , Kovtunov K.V. , Zhivonitko V.V. , Likholobov V.A. , Romanenko A.V. , Simonov P.A. , Nenajdenko V.G. , Shmatova O.I. , Muzalevskiy V.M. , Nechaev M.S. , Asachenko A.F. , Morozov O.S. , Dzhevakov P.B. , Osipov S.N. , Vorobyeva D.V. , Topchiy M.A. , Zotova M.A. , Ponomarenko S.A. , Borshchev O.V. , Luponosov Y.N. , Rempel A.A. , Valeeva A.A. , Stakheev A.Y. , Turova O.V. , Mashkovsky I.S. , Sysolyatin S.V. , Malykhin V.V. , Bukhtiyarova G.A. , Terentʹev A.O. , Krylov I.B.
Development of New Methods in Modern Selective Organic Synthesis: Preparation of Functionalized Molecules with Atomic Precision
Russian Chemical Reviews. 2014. V.83. N10. P.885-985. DOI: 10.1070/RC2014v83n10ABEH004471 WOS Scopus РИНЦ

ArticleLinkType.TRANSLATED_TO_ORIGINAL: Анаников В.П. , Хемчян Л.Л. , Иванова Ю.В. , Бухтияров В.И. , Сорокин А.М. , Просвирин И.П. , Вацадзе С.З. , Медведько А.В. , Нуриев В.Н. , Дильман А.Д. , Левин В.В. , Коптюг И.В. , Ковтунов К.В. , Живонитко В.В. , Лихолобов В.А. , Романенко А.В. , Симонов П.А. , Ненайденко В.Г. , Шматова О.И. , Музалевский В.М. , Нечаев М.С. , Асаченко А.Ф. , Морозов О.С. , Джеваков П.Б. , Осипов С.Н. , Воробьева Д.В. , Топчий М.А. , Зотова М.А. , Пономаренко С.А. , Борщев О.В. , Лупоносов Ю.Н. , Ремпель А.А. , Валеева А.А. , Стахеев А.Ю. , Турова О.В. , Машковский И.С. , Сысолятин С.В. , Малыхин В.В. , Бухтиярова Г.А. , Терентьев А.О. , Крылов И.Б.
Развитие методологии современного селективного органического синтеза: получение функционализированных молекул с атомарной точностью
Успехи химии. 2014. Т.83. №10. С.885-985. DOI: 10.1070/RC2014v083n10ABEH004471?locatt=label:RUSSIAN РИНЦ

Dates:

Submitted:	May 30, 2014
Published print:	Oct 31, 2014
Published online:	Nov 9, 2014

Identifiers:

Web of science	WOS:000344941600002
Scopus	2-s2.0-84907452759
Elibrary	23990954
AN	2014:2092188
CAN	162:189755

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