Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes
Full article
| Common |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Organic Letters
ISSN: 1523-7060
, E-ISSN: 1523-7052
|
| Output data |
Year: 2012,
Volume: 14,
Number: 17,
Pages: 4310-4313
Pages count
: 4
DOI:
10.1021/ol3015122
|
| Authors |
Ottenbacher Roman V.
1
,
Samsonenko Denis G.
2
,
Talsi Evgenii P.
3
,
Bryliakov Konstantin P.
3
|
| Affiliations |
| 1 |
Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
|
| 2 |
Nikolaev Institute of Inorganic Chemistry, Pr. Lavrentieva 3, Novosibirsk 630090, Russian Federation
|
| 3 |
Boreskov Institute of Catalysis, Pr. Lavrentieva 5,
Novosibirsk 630090, Russian Federation
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
12-03-00782
|
Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic CH groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).