Cyclization of Citronellal in a Supercritical Solvent in a Flow Reactor in the Presence of Al2O3
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244
, E-ISSN: 1531-863X
|
| Output data |
Year: 2012,
Volume: 86,
Number: 12,
Pages: 1917-1919
Pages count
: 3
DOI:
10.1134/S0036024412120035
|
| Tags |
Alumina, Citronellal, Cyclization, Isopulegol, Supercritical solvent |
| Authors |
Anikeev V.I.
1
,
Ilʹina I.V.
2
,
Volcho K.P.
2
,
Salakhutdinov N.F.
2
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
| 2 |
Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
11-08-00171
|
The reactivity of citronellal under supercritical solvent conditions in a flow reactor in the presence of Al2O3 is examined. It is shown that at 160°C, the main transformation product of citronellal is isopulegol, and when the temperature is increased to 190°C, they are monoterpenes with a para-menthane framework and myrcene.