Catalytic Hydrotreatment of Fast Pyrolysis Oil Using Bimetallic Ni–Cu Catalysts on Various Supports Full article
Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Output data | Year: 2012, Volume: 449, Pages: 121-130 Pages count : 10 DOI: 10.1016/j.apcata.2012.09.016 | ||||||
Tags | Catalytic hydrotreatment, HDO, Nickel-Copper, Pyrolysis oil, Support effects | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | European Commission | 518312 FP6-2004-ENERGY-3 BIOCOUP |
Abstract:
Bimetallic Ni–Cu catalysts on various supports (CeO2–ZrO2, ZrO2, SiO2, TiO2, rice husk carbon, and
Sibunite) with metal contents ranging from 7.5 to 9.0 (Ni) and 3.1–3.6 wt.% (Cu) for the inorganic supports
and 17.1–17.8 (Ni) and 7.1–7.8 (Cu) for the carbon supports were synthesised and screened for the
catalytic hydrotreatment of fast pyrolysis oil in a batch set-up (350 ◦C, 200 bar initial pressure). NiCu/TiO2
showed the highest activity (average activity of 576 NLhydrogen kgPO−1 gactive metal−1 for a 4 h batch time)
and gave a product oil with the most favourable properties, viz. a H/C ratio of 1.43, a low TG residue
(2.7 wt.%) and the highest solubility in a hydrocarbon solvent. The TiO2 based catalyst was characterised
as having moderate leaching levels of Ni and Cu metals (Ti remained unchanged), low carbon deposition
on the catalyst surface and limited metal sintering.
Cite:
Ardiyanti A.R.
, Khromova S.A.
, Venderbosch R.H.
, Yakovlev V.A.
, Melián-Cabrera I.V.
, Heeres H.J.
Catalytic Hydrotreatment of Fast Pyrolysis Oil Using Bimetallic Ni–Cu Catalysts on Various Supports
Applied Catalysis A: General. 2012. V.449. P.121-130. DOI: 10.1016/j.apcata.2012.09.016 WOS Scopus РИНЦ
Catalytic Hydrotreatment of Fast Pyrolysis Oil Using Bimetallic Ni–Cu Catalysts on Various Supports
Applied Catalysis A: General. 2012. V.449. P.121-130. DOI: 10.1016/j.apcata.2012.09.016 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 27, 2012 |
Accepted: | Sep 25, 2012 |
Published online: | Oct 5, 2012 |
Published print: | Dec 1, 2012 |
Identifiers:
Web of science | WOS:000313224500014 |
Scopus | 2-s2.0-84870476489 |
Elibrary | 20495090 |
Chemical Abstracts | 2012:1623237 |
Chemical Abstracts (print) | 158:108923 |
OpenAlex | W2033053816 |