Transformations of Several Monoterpenoids in the Presence of Aldehydes in Supercritical Solvents
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244
, E-ISSN: 1531-863X
|
| Output data |
Year: 2013,
Volume: 87,
Number: 3,
Pages: 382-387
Pages count
: 6
DOI:
10.1134/S0036024413030023
|
| Tags |
aldehydes, alumina, isopulegol, supercritical solvent, terpenoids, verbenol epoxide |
| Authors |
Anikeev V.I.
1
,
Sivtsev V.P.
2
,
Ilʹina I.V.
3
,
Korchagina D.V.
3
,
Statsenko O.B.
3
,
Volcho K.P.
3
,
Salakhutdinov N.F.
3
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
| 2 |
Novosibirsk State University
|
| 3 |
Vorozhtzov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
11-08-00171
|
The reactivity of verbenol epoxide and isopulegol in supercritical solvents in the presence of aromatic aldehydes was studied using a flow type reactor and a heterogeneous catalyst (Al2O3) or no catalyst. The intramolecular transformations or interactions of reagents with the solvent prevailed in all cases; the yield of the products of intermolecular reactions of terpenoids with aldehydes was up to 1%. The aldehydes did not interact with verbenol epoxide but produced a considerable effect on the distribution of its isomerization products.