Transformations of Several Monoterpenoids in the Presence of Aldehydes in Supercritical Solvents Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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Output data | Year: 2013, Volume: 87, Number: 3, Pages: 382-387 Pages count : 6 DOI: 10.1134/S0036024413030023 | ||||||
Tags | aldehydes, alumina, isopulegol, supercritical solvent, terpenoids, verbenol epoxide | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 11-08-00171 |
Abstract:
The reactivity of verbenol epoxide and isopulegol in supercritical solvents in the presence of aromatic aldehydes was studied using a flow type reactor and a heterogeneous catalyst (Al2O3) or no catalyst. The intramolecular transformations or interactions of reagents with the solvent prevailed in all cases; the yield of the products of intermolecular reactions of terpenoids with aldehydes was up to 1%. The aldehydes did not interact with verbenol epoxide but produced a considerable effect on the distribution of its isomerization products.
Cite:
Anikeev V.I.
, Sivtsev V.P.
, Ilʹina I.V.
, Korchagina D.V.
, Statsenko O.B.
, Volcho K.P.
, Salakhutdinov N.F.
Transformations of Several Monoterpenoids in the Presence of Aldehydes in Supercritical Solvents
Russian Journal of Physical Chemistry A. 2013. V.87. N3. P.382-387. DOI: 10.1134/S0036024413030023 WOS Scopus РИНЦ
Transformations of Several Monoterpenoids in the Presence of Aldehydes in Supercritical Solvents
Russian Journal of Physical Chemistry A. 2013. V.87. N3. P.382-387. DOI: 10.1134/S0036024413030023 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Аникеев В.И.
, Сивцев В.П.
, Ильина И.В.
, Корчагина Д.В.
, Стаценко О.Б.
, Волчо К.П.
, Салахутдинов Н.Ф.
Превращения некоторых монотерпеноидов в присутствии альдегидов в сверхкритических растворителях
Журнал физической химии. 2013. Т.87. №3. С.403-408. DOI: 10.7868/S0044453713030023 РИНЦ
Превращения некоторых монотерпеноидов в присутствии альдегидов в сверхкритических растворителях
Журнал физической химии. 2013. Т.87. №3. С.403-408. DOI: 10.7868/S0044453713030023 РИНЦ
Dates:
Submitted: | Feb 3, 2012 |
Published online: | Feb 3, 2013 |
Published print: | Mar 1, 2013 |
Identifiers:
Web of science | WOS:000314407800008 |
Scopus | 2-s2.0-84879657264 |
Elibrary | 20437382 |
Chemical Abstracts | 2013:189087 |
Chemical Abstracts (print) | 159:305628 |
OpenAlex | W2074440730 |